Rare earth metal oxide process including extracting rare earth metal from acidic solution with an ionic liquid composition

A method for preparing a rare earth metal oxide from a mixture of rare earth metals, said method comprising:

• contacting an acidic solution of the mixture of rare earth metals with a composition which comprises an ionic liquid to form an aqueous phase and a non-aqueous phase into which a rare earth metal has been selectively extracted;
• recovering the rare earth metal from the non-aqueous phase;
• and
• processing the recovered rare earth metal into a rare earth metal oxide,
• wherein the ionic liquid has the formula:
• [Cat+][X−]
• in which:
• [Cat+] represents a cationic species having the structure:
• where:
• [Y+] comprises ammonium, benzimidazolium, benzofuranium, benzothiophenium, benzotriazolium, borolium, cinnolinium, diazabicyclodecenium, diazabicyclononenium, 1,4-diazabicyclo[2.2.2]octanium, diazabicyclo-undecenium, dithiazolium, furanium, guanidinium, imidazolium, indazolium, indolinium, indolium, morpholinium, oxaborolium, oxaphospholium, oxazinium, oxazolium, iso-oxazolium, oxothiazolium, phospholium, phosphonium, phthalazinium, piperazinium, piperidinium, pyranium, pyrazinium, pyrazolium, pyridazinium, pyridinium, pyrimidinium, pyrrolidinium, pyrrolium, quinazolinium, quinolinium, iso-quinolinium, quinoxalinium, quinuclidinium, selenazolium, sulfonium, tetrazolium, thiadiazolium, iso-thiadiazolium, thiazinium, thiazolium, iso-thiazolium, thiophenium, thiuronium, triazinium, triazolium, iso-triazolium or uronium;
• each EDG represents an electron donating group;
• L1 is selected from C1-10 alkanediyl, C2-10 alkenediyl, C1-10 dialkanylether or C1-10 dialkanylketone;
• each L2 is independently selected from C1-2 alkanediyl, C2 alkenediyl, C1-2 dialkanylether or C1-2 dialkanylketone;
• and
• [X−] represents an anionic species.