Additive for nonaqueous electrolyte solutions, nonaqueous electrolyte solution, and electricity storage device
AssigneeSumitomo Seika Chemicals Co., Ltd.
InventorsYuki Kono, Shohei Fujimoto, Yasuyuki Takai, Koji Fujita
Life of this patent
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Abstract
Disclosed is an additive for nonaqueous electrolyte solutions, which includes a compound represented by the following formula (1): in the formula (1), Q represents an optionally substituted alkenylene group having 4 to 7 carbon atoms and forming a cyclic group together with the sulfur atom of the sulfonyl group, X represents a sulfonyl group, a phosphoryl group, or a carbonyl group, R1 represents an optionally substituted alkyl group having 1 to 4 carbon atoms or the like, and n represents 1 or 2.
Claims8
An additive for nonaqueous electrolyte solutions, comprising a compound represented by the following formula (1):
- wherein in the formula (1),
- Q represents an alkenylene group having 4 to 7 carbon atoms and optionally substituted with a fluorine atom and forming a cyclic group together with the sulfur atom of the sulfonyl group,
- X represents a sulfonyl group, a phosphoryl group, or a carbonyl group,
- n represents 1 or 2,
- wherein the group represented by O—X—(R1)n is bonded to the 3-position of the cyclic sulfone in the formula (1),
- wherein
- when X is a sulfonyl group, R1 is selected from the group consisting of
- an alkyl group having 1 to 4 carbon atoms and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkenyl group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an alkynyl group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an aryl group substituted with at least one selected from the group consisting of a fluorine atom and an alkyl group substituted with a fluorine atom,
- an alkoxy group having 1 to 4 carbon atoms and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkenyloxy group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an alkynyloxy group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom, and
- an aryloxy group optionally substituted with at least one selected from the group consisting of a fluorine atom, an alkyl group substituted with a fluorine atom, and an alkoxy group,
- when X is a phosphoryl group, R1 is selected from the group consisting of
- an alkyl group having 1 to 4 carbon atoms and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkenyl group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an alkynyl group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an aryl group optionally substituted with at least one selected from the group consisting of a fluorine atom, an alkyl group, and an alkyl group substituted with a fluorine atom,
- an alkoxy group having 1 to 4 carbon atoms and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkenyloxy group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an alkynyloxy group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom, and
- an aryloxy group optionally substituted with at least one selected from the group consisting of a fluorine atom, an alkyl group, an alkyl group substituted with a fluorine atom, and an alkoxy group, and
- when X is a carbonyl group, R1 is selected from the group consisting of
- a methyl group substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkyl group having 2 or 3 carbon atoms and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkyl group having 4 carbon atoms, other than a tert-butyl group, and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- a tert-butyl group substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkenyl group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an alkynyl group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an aryl group optionally substituted with at least one selected from the group consisting of a fluorine atom, an alkyl group, and an alkyl group substituted with a fluorine atom,
- an alkoxy group having 1 to 4 carbon atoms and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkenyloxy group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an alkynyloxy group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom, and
- an aryloxy group optionally substituted with at least one selected from the group consisting of a fluorine atom, an alkyl group, an alkyl group substituted with a fluorine atom, and an alkoxy group.
A nonaqueous electrolyte solution comprising:
- an additive;
- a nonaqueous solvent;
- and
- an electrolyte salt,
- wherein the additive comprises a compound represented by the following formula (1):
- wherein in the formula (1),
- Q represents an alkenylene group having 4 to 7 carbon atoms and optionally substituted with a fluorine atom and forming a cyclic group together with the sulfur atom of the sulfonyl group,
- X represents a sulfonyl group, a phosphoryl group, or a carbonyl group,
- R1 is selected from the group consisting of
- an alkyl group having 1 to 4 carbon atoms and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkenyl group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an alkynyl group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an aryl group optionally substituted with at least one selected from the group consisting of a fluorine atom or an alkyl group substituted with a fluorine atom,
- an alkoxy group having 1 to 4 carbon atoms and optionally substituted with at least one selected from the group consisting of a fluorine atom, an aryl group, and an aryl group substituted with a fluorine atom,
- an alkenyloxy group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom,
- an alkynyloxy group having 2 to 4 carbon atoms and optionally substituted with a fluorine atom, and
- an aryloxy group optionally substituted with at least one selected from the group consisting of a fluorine atom, an alkyl group, an alkyl group substituted with a fluorine atom, and an alkoxy group, and
- n represents 1 or 2,
- wherein the group represented by O—X—(R1)n is bonded to the 3-position of the cyclic sulfone in the formula (1),
- an amount of the compound represented by the formula (1) is 0.005% to 10% by mass based on a total mass of the nonaqueous electrolyte solution, and
- the electrolyte salt comprises a lithium salt.
Dependencies are inferred from the claim text.