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US 11,383,223 B2Granted
NOx trap catalyst support material composition
AssigneeSasol Germany GmbH
InventorsMarcos Schoneborn, Dirk Niemeyer, Thomas Harmening, Sandra Fibikar
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Abstract
The present invention relates to a method of making a support material composition comprising an Mg/AI oxide, a cerium oxide and at least another rare earth element oxide, to a support material composition and to the use of the support material composition as a nitrogen oxide storage component within a catalyst for treating exhaust gases to reduce NOx content.
Claims17
A method of preparing a support material composition, the composition comprising two phases:
- a first phase comprising a Mg/Al mixed oxide;
- and
- a second phase comprising a cerium based oxide, and rare-earth element(s) based oxide other than cerium oxide, wherein the second phase is a solid-solution;
- the method comprising the following steps:
- i) preparing an aqueous suspension of a Mg/Al mixed oxide precursor;
- ii) preparing an aqueous solution of a cerium salt;
- iii) preparing an aqueous solution of one or more rare-earth element salt(s) other than cerium salt;
- iv) combining, in any order, at least the aqueous suspension in step i), with the aqueous solution in step ii), and the aqueous solution of step iii) to form an aqueous mixture;
- v) dying the aqueous mixture to form a dried particulate material;
- and
- vi) calcining the dried particulate material;
- wherein the content of the one or more rare-earth element salt(s) other than cerium salt is between 5 and 50 wt. %, relative to the sum of
- the cerium salt from the aqueous solution of step ii) and
- the one or more rare earth element salt(s) other than cerium salt from the aqueous solution of step iii) and,
- wherein each of the salts are calculated as their oxides.
12 more elements
A support material composition comprising two phases:
- i) a first phase comprising a Mg/Al mixed oxide;
- and
- ii) a second phase comprising a cerium based oxide, and rare-earth element(s) based oxide other than cerium oxide, wherein the second phase is a solid-solution;
- the content of the first phase being at least 50 wt. % of the total support material composition,
- wherein the amount of Mg in the first phase is between 1 and 40 wt. %, calculated as MgO based on the weight of the first phase, calculated as MgO and Al2O3;
- and
- wherein the content of the rare-earth element(s) oxide other than cerium oxide in the second phase is between 10 and 35 wt. %,
- calculated as the rare earth element(s) oxide other than cerium oxide relative to the total second phase.
5 more elements
Dependencies are inferred from the claim text.