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US 11,380,884 B2Granted
Liquid composition for producing electrode composite material, method for producing electrode, and method for producing electrochemical element
AssigneeRicoh Company, Ltd.
InventorsSatoshi Nakajima, Eiko Hibino, Hiromichi Kuriyama, Keigo Takauji, Miku Ohkimoto, Shigeo Takeuchi, Masahiro Masuzawa
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Abstract
A liquid composition for an electrode composite material is provided. The liquid composition comprises an active material, a dispersion medium, and a polymerizable compound. A viscosity of the liquid composition at 25 degrees C. is a viscosity at which the liquid composition is dischargeable from a liquid discharge head.
Claims21
A liquid composition suitable for an electrode composite material, the composition comprising:
- an active material comprising of graphite having a mode diameter of 0.5 um or more;
- a dispersion medium:
- and
- a polymerizable compound,
- wherein a viscosity of the liquid composition at 25° C. is in a range of from 9.5 to 50 mPas,
- the polymerizable compound consists of (i) at least one polymerization initiator and/or catalyst, (ii) at least one acrylate, methacrylate, urethane acrylate resin, vinyl ester resin, unsaturated polyester, epoxy resin, oxetane resin, vinyl ether, a resin utilizing an ene-thiol reaction, or a mixture of two or more of any of these, and optionally (i) at least one sensitizing dye,
- the polymerization initiator functions substantially only as a polymerization initiator of polymerizable groups of monomers of the polymerizable compound:
- and
- wherein a 10% diameter (D10) of said graphite active material is 0.1 um or more, and 0.8 um or less.
6 more elements
A liquid composition suitable for an electrode composite material, the composition comprising:
- an active material comprising of graphite having a mode diameter of 0.5 um or more:
- a dispersion medium:
- and
- a polymerizable compound,
- wherein a viscosity of the liquid composition at 25° C. is in a range of from 9.5 to 50 mPas,
- the polymerization initiator is at least one selected from the group consisting of α-hydroxyacetophenone, α-aminoacetophenone, 4-aroyl-1,3-dioxolane, benzyl ketal, 2,2-diethoxyacetophenone, p-dimethylaminoacetophene, p-dimethylaminopropiophenone, benzophenone, 2-chlorobenzophenone, 4,4′-dichlorobenzophenone, 4,4′-bis(diethylamino)-benzophenone, Michler's ketone, benzil, benzoin, benzyl dimethyl ketal, tetramethylthiuram monosulfide, thioxanthone, 2-chlorothioxanthone, 2-methylthioxanthone, azobisisobutyronitrile, benzoin peroxide, di-tertbutyl peroxide, (1-hydroxycyclohexyl)-phenylketone, 2-hydroxy-2-methyl-1-phenyl-1-one, 1-(4-isopropylphenyl)-2-hydroxy-2-methylpropane-1-one, methyl benzoylformate, a benzoin alkyl ether, 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)butanone-1, 2,2-dimethoxy-1,2-diphenylethane-1-one, bis(η5-2,4-cyclopentadiene-1-yl)-bis[2,6-difluoro-3-(1H-pyrrole-1-yl)phenyl] titanium, bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide, 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropane-1-one, 2-hydroxy-2-methyl-1-phenylpropane-1-one, bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine oxide, 1-[4-(2-hydroxyethoxy)phenyl]-2-hydroxy-2-methyl-1-propane-1-one, monoacylphosphine oxide, disacylphosphine oxide, titanocene, fluorescein, anthraquinone, thioxanthone, xanthone, lophine dimer, a trihalomethyl compound, a dihalomethyl compound, an active ester compound, an organic boron compound, a bisazide compound, azobisisobutyronitrile, onium salt, diazonium salt, quinone diazide, organic halide, aromatic sulfonate, bisulfone compound, sulfonyl compounds, sulfonate, sulfonium salt, sulfamide, iodonium salt, sulfonyl diazomethane compound, and a mixture of two or more of these photoradical generators or thermal polymerization initiators, or photoacid generators;
- and
- wherein a 10% diameter (D10) of said graphite active material is 0.1 um or more, and 0.8 um or less.
5 more elements
Dependencies are inferred from the claim text.