Bulk nickel-silicon-boron glasses bearing chromium
AssigneeGlassimetal Technology, Inc.
InventorsJong Hyun Na, Michael Floyd, Glenn Garrett, Marios D. Demetriou, William L. Johnson
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Abstract
Nickel based alloys capable of forming bulk metallic glass are provided. The alloys include Ni—Cr—Si—B compositions, with additions of P and Mo, and are capable of forming a metallic glass rod having a diameter of at least 1 mm. In one example of the present disclosure, the Ni—Cr—Mo—Si—B—P composition includes about 4.5 to 5 atomic percent of Cr, about 0.5 to 1 atomic percent of Mo, about 5.75 atomic percent of Si, about 11.75 atomic percent of B, about 5 atomic percent of P, and the balance is Ni, and wherein the critical metallic glass rod diameter is between 2.5 and 3 mm and the notch toughness between 55 and 65 MPa m1/2.
Claims8
A metallic glass having the formula consisting of:
- Ni(100-a-b-c-d)CraSibBcPd
- wherein the atomic percent of chromium (Cr) a is between 3 and 8, the atomic percent of silicon (Si) b is greater than 5 and not greater than 12, the atomic percent of boron (B) c is between 9 and 13, the atomic percent of phosphorus (P) d is between 0.5 and 8, and the balance is Ni, and wherein the critical rod diameter of the metallic glass is at least 2 mm.
A metallic glass having the formula consisting of:
- Ni(100-a-b-c-d-e)CraSibBcPdXe
- wherein the atomic percent of chromium (Cr) a is between 3 and 8, the atomic percent of silicon (Si) b is greater than 5 and not greater than 12, the atomic percent of boron (B) c is between 9 and 13, the atomic percent of phosphorus (P) d is between 0.5 and 8, wherein X is one or more optional elements selected from a group consisting of Co, Mn, W, Ru, Re, Pd, Pt, Nb, V, and Ta, wherein the atomic percent of the optional elements (X) e is up to 2, and wherein the balance is Ni;
- and
- wherein the critical rod diameter of the metallic glass is at least 2 mm.
Dependencies are inferred from the claim text.