Method for converting N,N-dialkylamide compound into ester compound using complex of fourth-period transition metal as catalyst
AssigneesTakasago International Corporation, Osaka University
InventorsKazushi Mashima, Haruki Nagae, Takahiro Hirai, Daiki Kato, Shusei Soma, Shinya Akebi, Shoko Akiyama, Kazuhiko Matsumura, Yoshimasa Matsushima
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Abstract
A method for converting an N,N-dialkylamide compound into an ester compound includes using a fourth period transition metal complex as a catalyst. The fourth period transition metal complex is obtained by a reaction of a precursor having a fourth period transition metal with a nitrogen-containing compound or a phosphorus-containing compound.
Claims3
A fourth period transition metal complex, which is obtained by a reaction of a precursor having a fourth period transition metal with a nitrogen-containing compound in the presence of an alcohol or alkoxide,
- wherein the fourth period transition metal is selected from the group consisting of scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), cobalt (Co), nickel (Ni), and copper (Cu), and
- the nitrogen-containing compound is bipyridine which optionally has substituent(s) or 1,10-phenanthroline which optionally has substituent(s).
A μ-oxo-dimer complex of the following general formula (1),
- wherein M represents a fourth period transition metal,
- A represents a carboxylic acid residue, a beta-diketonate, a beta-diketoiminate, or a beta-diketiminate,
- in the case where A represents the carboxylic acid residue, x represents 2, and in the case where A represents the beta-diketonate, beta-diketoiminate, or beta-diketiminate, x represents 1,
- L represents a nitrogen-containing compound or a phosphorus-containing compound, and
- Z represents a lower alkyl group which optionally has substituent(s), a lower alkoxy group which optionally has substituent(s), a lower alkenyl group which optionally has substituent(s), a lower alkynyl group which optionally has substituent(s), a halo-lower alkyl group which optionally has substituent(s), a halo-lower alkenyl group which optionally has substituent(s), a halo-lower alkynyl group which optionally has substituent(s), a cyclic hydrocarbon group which optionally has substituent(s), or a heterocyclic group which optionally has substituent(s),
- the μ-oxo-dimer complex being obtained by a reaction of a metal complex having a ligand selected from the group consisting of beta-diketonates, beta-diketoiminates, and beta-diketiminates, or a carboxylate of a fourth period transition metal, with a nitrogen-containing compound or phosphorus-containing compound, which are added thereto, in the presence of an alcohol or alkoxide.
Dependencies are inferred from the claim text.