Additive for hydraulically setting compositions
AssigneeConstruction Research & Technology GmbH
InventorsTorben Gädt, Harald Grassl, Luc Nicoleau, Alfons Smeets
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Abstract
The present invention relates to an additive for hydraulically setting compositions comprising a colloidally disperse preparation comprising at least one salt of a polyvalent metal cation with at least one organic phosphonate and/or phosphate compound as anion and at least one polymeric dispersant comprising anionic and/or anionogenic groups and polyether side chains. The additive is especially suitable as slump retainer and for improving early strength.
Claims19
An additive for hydraulically setting compositions, comprising an aqueous colloidally disperse preparation comprising
- a) at least one salt of at least one polyvalent metal cation with at least one organic phosphonate and/or organic phosphate compound as anion, optionally in a mixture with at least one compound capable of releasing an inorganic anion selected from carbonate, oxalate, silicate, phosphate, polyphosphate, phosphite, borate, aluminate and sulphate, which forms a sparingly soluble salt with the polyvalent metal cation and
- b) at least one polymeric dispersant comprising anionic and/or anionogenic groups and polyether side chains,
- wherein the polyvalent metal cation selected from Al3+, Fe3+, Fe2+, Zn2+, Mn2+, Cu2+, Mg2+, Ca2+, Sr2+, Ba2+ and mixtures thereof, and wherein the metal cation is present in an amount corresponding to the following formula (a):
- 0.1
- <
- ∑
- i
-
- z
- K
- ,
- i
- *
- n
- K
- ,
- i
- ∑
- j
-
- z
- S
- ,
- j
- *
- n
- S
- ,
- j
- <
- 50.
- (
- a
- )
- where
- zK,i is the magnitude of the charge of the polyvalent metal cation,
- nK,i is the number of moles of the polyvalent metal cation,
- zS,j is the magnitude of the charge of the anionic and anionogenic group present in the polymeric dispersant,
- nS,j is the number of moles of the anionic and anionogenic group present in the polymeric dispersant,
- the indices i and j are independent of one another and are an integer greater than 0, where i is the number of different kinds of polyvalent metal cations and j is the number of different kinds of anionic and anionogenic groups present in the polymeric dispersant.
Dependencies are inferred from the claim text.