Blocked polyisocyanate composition, one-component coating composition, coating film, and coated article
AssigneeAsahi Kasei Kabushiki Kaisha
InventorsMasakazu Yamauchi, Satoshi Takeno
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Abstract
The present invention provides a blocked polyisocyanate composition comprising a blocked polyisocyanate formed through blocking at least a part of isocyanate groups possessed by a polyisocyanate derived from one or two or more diisocyanates selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate with an active methylene-based compound comprising a malonic acid diester, wherein a specific molar ratio calculated from contents (mol %) of isocyanurate groups, iminooxadiazinedione groups, uretdione groups, and allophanate groups is 0.05 or more and 0.60 or less.
Claims7
A blocked polyisocyanate composition comprising a blocked polyisocyanate formed through blocking at least a part of isocyanate groups possessed by a polyisocyanate derived from one or two or more diisocyanates selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate with an active methylene-based compound comprising a malonic acid diester, wherein
- a specific molar ratio represented by formula (1) is 0.05 or more and 0.60 or less:
- specific molar ratio=(B+C+D)/(A+B+C+D) (1)
- wherein A represents a content (mol %) of isocyanurate groups represented by formula (I);
- B represents a content (mol %) of iminooxadiazinedione groups represented by formula (II);
- C represents a content (mol %) of uretdione groups represented by formula (III);
- and D represents a content (mol %) of allophanate groups represented by formula (IV),
- and
- a monohydric alcohol selected from the group consisting of methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, 2-butanol, t-butanol, n-amyl alcohol, isoamyl alcohol, 2-methyl-1-butanol, n-hexanol, 2-methyl-1-pentanol, 2-ethyl-1-butanol, n-heptanol, n-octanol, and 2-ethyl-1-hexanol, and
- wherein the monohydric alcohol is in an amount of 10 eq % or more and 500 eq % or less of blocked isocyanate groups.
Dependencies are inferred from the claim text.