Organic compounds

A woody, ambery perfume composition, free or substantially free of 2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-5-(1-methylpropyl)-1,3-dioxane and comprising a mixture of at least three perfume ingredients selected from:

• a) at least one primary perfume ingredient selected from the group consisting of (1′R,3S,6′S)-1-(2′,2′,6′-trimethyl-1′-cyclohexyl)-3-hexanol, (1′S,3S,6′R)-1-(2′,2′,6′-trimethyl-1′-cyclohexyl)-3-hexanol or any mixture thereof;
• an isomer or mixture of isomers of octahydro-2,2,5,8,8,9a-hexamethyl-4H-4a,9-methanoazuleno[5,6-d]-1,3-dioxole;
• an isomer or mixture of isomers of 2-(TETRAMETHYLTRICYCLO[6.2.1.0]UNDEC-4/5-EN-5-YL)PROPANOL having the formula
• and an isomer or mixture of isomers of DECAHYDRO-2,2,6,6,7,8,8-HEPTAMETHYL INDENOFURAN;
• AND
• b) at least one secondary perfume ingredient selected from the group consisting of (Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene;
• 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran;
• (ethoxymethoxy)cyclododecane;
• 6-(sec-butyl)quinoline;
• (1R,6S,8aS)-6-methoxy-1,4,4,6-tetramethyloctahydro-1H-5,8a-methanoazulene;
• 2-(tert-pentyl)cyclohexyl acetate;
• 2-(2-(3,3,5-trimethylcyclohexyl)acetyl)cyclopentanone;
• (1aS,2aR,3R,5aS,7R,7aR)-octahydro-3,6,6,7a-tetramethyl-2H-2a,7-methanozuleno 5,6-b oxirene;
• 3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan;
• 2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl formate;
• 1-(1,2,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethanone;
• 2,2,7,7-tetramethyltricyclo[6.2.1.01,6] undecanethan-5-one;
• (Z)-3,4,5,6,6-pentamethylhept-3-en-2-one;
• 3,4,5,6,6-pentamethylheptan-2-ol;
• 1-((1S,8aS)-1,4,4,6-tetramethyl-2,3,3a,4,5,8-hexahydro-1H-5,8a-methanoazulen-7-yl)ethanone;
• 2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane;
• 2′,2′,3,7,7-pentamethylspiro[bicyclo[4.1.0]heptane-2,5′-[1,3]dioxane];
• 1-((2E,5Z,9Z)-2,7,8-trimethylcyclododeca-2,5,9-trien-1-yl)ethanone;
• 1-((1S,8aS)-1,4,4,6-tetramethyl-2,3,3a,4,5,8-hexahydro-1H-5,8a-methanoazulen-7-yl)ethanone;
• 2-methyl-4-(5,6,6-trimethylbicyclo[2.2.1]hept-2-yl-cyclohexanone;
• 1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol;
• 3,8,8,11a-tetramethyldodecahydro-1H-3,5a-epoxynaphtho[2,1-c]oxepine;
• 3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan;
• (1R,2S,4R)-2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane];
• 2-(sec-butyl)-1-vinylcyclohexyl acetate;
• 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone;
• 2-(sec-butyl)-1-methylcyclohexyl acetate;
• 2-methylundecanoic acid;
• 2-cyclohexylhepta-1,6-dien-3-one;
• decahydro-2,6,6,7,8,8-hexamethyl-2H-indeno[4,5-b]furan;
• and hexahydro-1′,1′,5′,5′-tetramethyl-spiro(1,3-dioxolane-2,8′(5′H)-(2H-2,4a)methanonaphthalene),
• wherein (1′R,3S,6′S)-1-(2′,2′,6′-trimethyl-1′-cyclohexyl)-3-hexanol, (1′S,3S,6′R)-1-(2′,2′,6′-trimethyl-1′-cyclohexyl)-3-hexanol or any mixture thereof is present in an amount of 4.5 to 90 wt % based on the total weight of said composition,
• wherein the composition comprises an isomer or mixture of isomers of octahydro-2,2,5,8,8,9a-hexamethyl-4H-4a,9-methanoazuleno[5,6-d]-1,3-dioxole and/or an isomer or mixture of isomers of 2-(tetramethyltricyclo[6.2.1.0]undec-4/5-en-5-yl)propanol and/or an isomer or mixture of isomers of decahydro-2,2,6,6,7,8,8-heptamethyl indenofuran;
• and
• wherein the composition comprises one or more of 2′,2′,3,7,7-pentamethylspiro[bicyclo[4.1.0]heptane-2,5′-[1,3]dioxane], 2-cyclohexylhepta-1,6-dien-3-one, 2-methylundecanoic acid, and 2-methyl-4-(5,6,6-trimethylbicyclo[2.2.1]hept-2-yl-cyclohexanone.