Catalysts and methods of making the same

A catalyst comprising:

• (i) at least one microporous material, wherein the microporous material is a zeolite, a molecular sieve comprising aluminophosphate and/or silicoaluminophosphate, or combinations thereof;
• (ii) a porous organosilica material binder, which is a polymer comprising independent units of a monomer selected from the group consisting of:
• (a) a monomer of Formula [Z15Z16SiCH2]3 (I), wherein each Z15 represents a hydroxyl group, a C1-C4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer and each Z16 represents a hydroxyl group, a C1-C4 alkoxy group, a C1-C4 alkyl group, or an oxygen atom bonded to a silicon atom of another monomer;
• and
• (b) a cyclic polyurea monomer of Formula
• wherein each R1 independently is a X5OX6X7SiX8 group, wherein each X5 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silicon atom of another monomer unit;
• X6 and X7 each independently represent a hydroxyl group, a C1-C4 alkyl group, a C1-C4 alkoxy group, or an oxygen atom bonded to a silicon atom of another monomer unit;
• and each X8 represents a C1-C8 alkylene group bonded to a nitrogen atom of the cyclic polyurea;
• and
• (iii) at least one catalyst metal, wherein the at least one catalyst metal is incorporated into the microporous material, the porous organosilica material binder and/or a catalyst particle comprising the at least one microporous material bound with the polymer,
• and the porous organosilica material binder is present in the catalyst in an amount of at least about 1.0 wt % based on the total weight of the microporous material and the porous organosilica material binder.