# US 11,309,106 B2 · Device protected by PTC element > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,309,106 B2 - Document ID: US11309106B2 - Status: Granted - Kind: B2 - Application number: 16/477,776 - Filed: 2018-01-10 - Published: 2019-12-05 - Granted: 2022-04-19 - Earliest claimed: 2017-01-13 - Assignees: Liffelfuse Japan G. K. - Applicants: Littelfuse Japan G.K. - Inventors: Arata Tanaka; Keiichiro Nomura; Satoshi Sakamoto - Web page: https://patentgrep.com/patent/US11309106B2 ## CPC - H01C 1/1406: {Terminals or electrodes formed on resistive elements having positive temperature coefficient} - H01C 7/028: {consisting of organic substances} - H01C 1/142: the terminals or tapping points being coated on the resistive element - H01C 1/144: the terminals or tapping points being welded or soldered - H01C 7/027: {consisting of conducting or semi-conducting material dispersed in a non-conductive organic material} - H01C 7/13: current-responsive - H02H 9/026: {Current limitation using PTC resistors, i.e. resistors with a large positive temperature coefficient} - H01C 7/02: having positive temperature coefficient - H02H 5/042: {using temperature dependent resistors} - H01C: RESISTORS - H02H: EMERGENCY PROTECTIVE CIRCUIT ARRANGEMENTS (indicating or signalling undesired working conditions G01R, e.g. G01R31/00, G08B; locating faults along lines G01R31/08; emergency protective devices H01H) ## Abstract The present invention provides an apparatus having a protecting element for protecting the apparatus in an emergency, wherein the protecting element is a polymer PTC element, the polymer PTC element has a polymer PTC member, and the polymer PTC member is formed from a polymer composition containing a polyvinylidene fluoride as a main component. ## Claims ### Claim 1 An apparatus comprising a protecting element for protecting the apparatus in an emergency, wherein the protecting element is a polymer positive temperature coefficient (PTC) member comprising: a polymer PTC composition comprising polyvinylidene fluoride (PVDF) and one or more polymer components, the PVDF further comprising: a mass of at least 55% of the polymer PTC composition; an average molecular weight of between 5×103 and 1×106; and a crystallinity of between 30% and 60%; and an electrically conductive filler, wherein the electrically conductive filler is dispersed in the polymer composition; wherein the PTC member has a resistance change rate of between 0.74 and 0.89 after being immersed in oil for 200 hours. ### Claim 2 (depends on 1) The apparatus of claim 1, wherein the one or more polymer components has a resistance to oils, fats, and solvents. ### Claim 3 (depends on 1) The apparatus of claim 1, wherein the one or more other polymer components comprises an ethylene-tetrafluoroethylene copolymer (ETFE). ### Claim 4 (depends on 3) The apparatus of claim 3, wherein the polymer PTC composition comprises 58 mass % of PVDF and 10 mass % of ETFE and the electrically conductive filler comprises 32 mass % Carbon Black. ### Claim 5 (depends on 4) The apparatus of claim 4, further comprising a copper foil disposed on either side of the polymer PTC composition. ### Claim 6 (depends on 5) The apparatus of claim 5, further comprising a copper plating disposed adjacent the copper foil. ### Claim 7 (depends on 6) The apparatus of claim 6 further comprising a nickel plating disposed adjacent to the copper plating at opposing ends of the polymer PTC composition. ### Claim 8 (depends on 7) The apparatus of claim 7, further comprising a tin plating disposed adjacent to the nickel plating such that the nickel plating is disposed between the tin plating and the copper plating. ### Claim 9 (depends on 3) The apparatus of claim 3, wherein the polymer PTC composition comprises 56 mass % of PVDF and 10 mass % of ETFE and the electrically conductive filler comprises 34 mass % Carbon Black. ### Claim 10 (depends on 9) The apparatus of claim 9, further comprising a copper foil and a prepreg, the polymer PTC composition being divided into a first portion and a second portion, with the first portion being substantially surrounded with the copper foil, the second portion being substantially surrounded with the copper foil, wherein the first portion, the prepreg, and the second portion forming a sandwich. ### Claim 11 (depends on 10) The apparatus of claim 10, further comprising copper plating disposed on either side of the sandwich. ### Claim 12 (depends on 11) The apparatus of claim 11, further comprising nickel plating and tin plating, wherein the nickel plating is disposed adjacent to the copper plating and the tin plating is disposed adjacent to the nickel plating such that the nickel plating is between the copper plating and the tin plating. ### Claim 13 (depends on 1) The apparatus of claim 1, wherein the one or more other polymer components is selected from a group consisting of polyethylene, acrylic polymers, methacrylic polymers, and fluoropolymers. ### Claim 14 (depends on 1) The apparatus of claim 1, wherein the electrically conductive filler is selected from a group consisting of carbon black, graphite, black lead, a carbonaceous material, a metal, a conductive metal oxide, a conductive ceramic, a conductive polymer, and a combination of one or more of carbon black, graphite, black lead, carbonaceous material, metal, conductive metal oxide, conductive ceramic, and conductive polymer. ### Claim 15 (depends on 14) The apparatus of claim 14, wherein the electrically conductive filler comprises a carbonaceous material selected from a group consisting of carbon fibers, carbon nanotubes, glassy carbon, carbon beads, carbon black, and graphite. ### Claim 16 (depends on 14) The apparatus of claim 14, wherein the electrically conductive filler comprises a metal selected from a group consisting of gold, silver, copper, nickel, aluminum, tungsten, alloy of gold, alloy of silver, alloy of copper, alloy of nickel, alloy of aluminum, and alloy of tungsten. ### Claim 17 (depends on 14) The apparatus of claim 14, wherein the electrically conductive filler comprises a conductive ceramic selected from a group consisting of carbide, titanium borate, titanium nitride, titanium silicide, zirconium silicide, niobium silicide, molybdenum silicide, tantalum silicide, and tungsten silicide. ### Claim 18 (depends on 14) The apparatus of claim 14, wherein the electrically conductive filler comprises a metal oxide selected from a group consisting of metal oxide including indium-tin oxide, lithium-manganese complex oxide, vanadium pentoxide, tin oxide, zinc oxide, and potassium titanate. ### Claim 19 (depends on 14) The apparatus of claim 14, wherein the electrically conductive material is in a powder state.