# US 11,306,259 B2 · Method and apparatus for self-heat-extracting flash evaporation of sulfuric acid alkylation reaction product

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- Number: US 11,306,259 B2
- Document ID: US11306259B2
- Status: Granted
- Kind: B2
- Application number: 16/665,233
- Filed: 2019-10-28
- Published: 2020-05-28
- Granted: 2022-04-19
- Earliest claimed: 2018-11-28
- Assignees: East China University of Science and Technology
- Applicants: East China University of Science and Technology
- Inventors: Zhishan Bai; Yan Zhang; Xiaoyong Yang; Huiqing Luo
- Web page: https://patentgrep.com/patent/US11306259B2

## CPC

- C10G 29/28: containing sulfur as the only hetero atom, e.g. mercaptans, or sulfur and oxygen as the only hetero atoms
- B01D 3/06: Flash distillation
- C07C 2/62: with acids
- C07C 7/005: {Processes comprising at least two steps in series}
- C10G 57/005: {with alkylation}
- C10G 2300/1081: Alkanes
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

The present disclosure relates to a method and an apparatus for self-heat-extracting flash evaporation of a sulfuric acid alkylation reaction product. There is provided a method for self-heat-extracting flash evaporation of a sulfuric acid alkylation reaction product. One step is to coalesce and vaporize a preliminarily distributed sulfuric acid alkylation reaction product to cause preliminary vaporization of a hydrocarbon therein, thereby taking heat away and preliminarily separating the hydrocarbon from sulfuric acid. Another step is to subject the preliminarily separated alkylation reaction to reinforced separation, where the hydrocarbon is further vaporized to take heat away and further separate the hydrocarbon from the sulfuric acid. There is also provided an apparatus for self-heat-extracting flash evaporation of a sulfuric acid alkylation reaction product.

## Claims

### Claim 1

A method for self-heat-extracting flash evaporation of a sulfuric acid alkylation reaction product, comprising the following steps:
(a) introducing a sulfuric acid alkylation reaction product to a coalescence-vaporization unit;
(b) distributing the sulfuric acid alkylation reaction product throughout the coalescence-vaporization unit thereby producing a preliminarily distributed sulfuric acid alkylation product;
(c) coalescing and vaporizing the preliminarily distributed sulfuric acid alkylation reaction product to cause preliminary vaporization of a hydrocarbon therein, thereby taking heat away and separating a preliminarily separated alkylation reaction product comprising hydrocarbon from the sulfuric acid,
wherein said preliminarily distributed sulfuric acid alkylation reaction product is coalesced through one or more parallel coalescence-vaporization assemblies comprising a coalescence module and a vaporization module installed in an annular gap of a support framework comprising a plurality of concentric cylinders,
wherein said preliminarily distributed sulfuric acid alkylation reaction product flows through 1-50 mm holes through and around said concentric cylinders to reach said coalescence module and said vaporization module,
wherein a ratio of a perforated area to an unperforated area in a wall portion of one of said concentric cylinders is from 1:1 to 1.5:1, and
wherein when said preliminarily distributed sulfuric acid alkylation reaction product flows through said coalescence module, said coalescence module coalesces the preliminarily distributed sulfuric acid alkylation reaction product; and
(d) subjecting the preliminarily separated alkylation reaction product obtained in step (c) to reinforced separation by flowing said preliminarily separated alkylation reaction product through a circular arc plate, a circular arc corrugated plate, a circular arc stepped plate, or a bellmouth-shaped tubular structure formed by the above-mentioned circular arc plate structure and a cylindrical welded member,
wherein said preliminarily separated alkylation reaction product flows through holes opened through the circular arc plate, the circular arc corrugated plate, the circular arc stepped plate, or the bellmouth-shaped tubular structure having a diameter of 1 to 50 mm, said holes creating a ratio of a perforated area to an unperforated area of the circular arc plate, the circular arc corrugated plate, the circular arc stepped plate, or the bellmouth-shaped tubular structure from 1:1 to 2:1, and
wherein the hydrocarbon is further vaporized to take heat away from the preliminary separated alkylation reaction product and further separate the hydrocarbon from the sulfuric acid in the preliminarily separated alkylation reaction product.

### Claim 2 (depends on 1)

The method of claim 1, wherein, in step (c), the preliminarily distributed sulfuric acid alkylation reaction product is preliminarily distributed through a liquid distributor and a bubble cap plate; and the coalescence and the vaporization are performed using a coalescence-vaporization unit comprising the one or more parallel coalescence-vaporization assemblies, wherein the preliminarily distributed sulfuric acid alkylation reaction product flows into a center of the coalescence-vaporization assemblies and, in its radial direction, flows sequentially through an inner wall of said support framework, said coalescence module, said vaporization module, and an outer wall of the support framework.

### Claim 3 (depends on 2)

The method of claim 2, wherein, in step (d), the reinforced separation is conducted using a reinforced separation unit, wherein sulfuric acid droplets which are not separated timely are spread by an acid-hydrocarbon separation-coalescence baffle in the reinforced separation unit into a film on a surface thereof, adhered and detached, thereby further separating the hydrocarbon from the sulfuric acid; while the hydrocarbon is further vaporized, takes heat away, and is discharged from a gas phase outlet.