# US 11,306,053 B2 · Ester compound and lubricating oil base oil

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- Number: US 11,306,053 B2
- Document ID: US11306053B2
- Status: Granted
- Kind: B2
- Application number: 17/051,772
- Filed: 2019-01-31
- Published: 2021-07-29
- Granted: 2022-04-19
- Earliest claimed: 2018-05-01
- Assignees: Daisan Kasei Kabushiki Kaisha; Jnc Corporation
- Applicants: Daisan Kasei Co., Ltd; Jnc Corporation
- Inventors: Yasuo Urata; Tetsuya Isaka; Taichi Shimada
- Web page: https://patentgrep.com/patent/US11306053B2

## CPC

- C07C 69/24: esterified with monohydroxylic compounds
- C07C 67/08: by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
- C07C 69/44: Adipic acid esters
- C07C 69/533: Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C 69/58: Esters of straight chain acids with eighteen carbon atoms in the acid moiety
- C07C 69/82: Terephthalic acid esters
- C10M 105/34: of monocarboxylic acids
- C10M 105/36: of polycarboxylic acids
- C10M 177/00: Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
- C10M 2207/281: of (cyclo)aliphatic monocarboxylic acids
- C10M 2207/2815: used as base material
- C10M 2207/2825: used as base material
- C10M 2207/2855: used as base material
- C10N 2020/02: Viscosity; Viscosity index
- C10N 2030/02: Pour-point; Viscosity index
- C10N 2070/00: Specific manufacturing methods for lubricant compositions
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C10M: LUBRICATING COMPOSITIONS (well drilling compositions C09K8/02); USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION (mould release, i.e. separating, agents for metals B22C3/00, for plastics or substances in a plastic state, in general B29C33/56, for glass C03B40/02; textile lubricating compositions D06M11/00, D06M13/00, D06M15/00; immersion oils for microscopy G02B21/33)
- C10N: INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

## Abstract

[Problem] An ester compound having low viscosity, excellent fluidity even at low temperatures, and a high viscosity index; and a lubricating oil base oil containing said compound are provided. [Solution] The present invention provides an ester compound indicated by formula (I). Formula (I) (in formula (I), R1 is a hydrocarbon group having 1 to 35 carbon atoms and at least one hydrogen in the hydrocarbon group may be independently substituted with a group indicated by formula (II)). Formula (II) (in formula (II), R2 is a linear alkyl having 1 to 30 carbon atoms or a branched alkyl having 3 to 30 carbon atoms.)

## Claims

### Claim 1

An ester compound represented by Formula (I):
in Formula (I), R1 is a hydrocarbon group having 1 to 35 carbon atoms, and at least one hydrogen in the hydrocarbon group may be independently substituted with a group represented by Formula (II);
in Formula (II), R2 is a linear alkyl having 1 to 30 carbon atoms or a branched alkyl having 3 to 30 carbon atoms.

### Claim 2 (depends on 1)

The ester compound according to claim 1, which is represented by Formula (I):
in Formula (I), R1 is a linear alkyl having 1 to 35 carbon atoms, a branched alkyl having 3 to 35 carbon atoms, or a linear alkenyl having 4 to 24 carbon atoms, in which at least one hydrogen in the alkyl and the alkenyl may be independently substituted with a group represented by Formula (II);
in Formula (II), R2 is a linear alkyl having 1 to 30 carbon atoms or a branched alkyl having 3 to 30 carbon atoms.

### Claim 3 (depends on 1)

The ester compound according to claim 1, which is represented by Formula (I):
in Formula (I), R1 is phenyl, cyclohexyl, or cyclohexenyl, in which at least one hydrogen in these rings may be independently substituted with a linear alkyl having 1 to 10 carbon atoms or a group represented by Formula (II);
in Formula (II), R2 is a linear alkyl having 1 to 30 carbon atoms or a branched alkyl having 3 to 30 carbon atoms.

### Claim 4 (depends on 1)

The ester compound according to claim 1,
wherein at least one hydrogen in R1 is substituted with a group represented by Formula (II), and
R2 is a group represented by Formula (III):

### Claim 5 (depends on 1)

A lubricating oil base oil, comprising:
the ester compound according to claim 1.

### Claim 6 (depends on 1)

A method for producing the ester compound according to claim 1, the method comprising:
a step of subjecting 10-ethyl-7-tetradecanol and carboxylic acid to esterification reaction.

### Claim 7 (depends on 2)

The ester compound according to claim 2,
wherein at least one hydrogen in R1 is substituted with a group represented by Formula (II), and
R2 is a group represented by Formula (III):

### Claim 8 (depends on 3)

The ester compound according to claim 3,
wherein at least one hydrogen in R1 is substituted with a group represented by Formula (II), and
R2 is a group represented by Formula (III):

### Claim 9 (depends on 2)

A lubricating oil base oil, comprising:
the ester compound according to claim 2.

### Claim 10 (depends on 3)

A lubricating oil base oil, comprising:
the ester compound according to claim 3.

### Claim 11 (depends on 4)

A lubricating oil base oil, comprising:
the ester compound according to claim 4.

### Claim 12 (depends on 7)

A lubricating oil base oil, comprising:
the ester compound according to claim 7.

### Claim 13 (depends on 8)

A lubricating oil base oil, comprising:
the ester compound according to claim 8.

### Claim 14 (depends on 2)

A method for producing the ester compound according to claim 2, the method comprising:
a step of subjecting 10-ethyl-7-tetradecanol and carboxylic acid to esterification reaction.

### Claim 15 (depends on 3)

A method for producing the ester compound according to claim 3, the method comprising:
a step of subjecting 10-ethyl-7-tetradecanol and carboxylic acid to esterification reaction.

### Claim 16 (depends on 4)

A method for producing the ester compound according to claim 4, the method comprising:
a step of subjecting 10-ethyl-7-tetradecanol and carboxylic acid to esterification reaction.

### Claim 17 (depends on 7)

A method for producing the ester compound according to claim 7, the method comprising:
a step of subjecting 10-ethyl-7-tetradecanol and carboxylic acid to esterification reaction.

### Claim 18 (depends on 8)

A method for producing the ester compound according to claim 8, the method comprising:
a step of subjecting 10-ethyl-7-tetradecanol and carboxylic acid to esterification reaction.
