# US 11,305,570 B2 · Dye sublimation ready coating for low temperature plastic substrates

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- Number: US 11,305,570 B2
- Document ID: US11305570B2
- Status: Granted
- Kind: B2
- Application number: 16/290,915
- Filed: 2019-03-03
- Published: 2019-06-27
- Granted: 2022-04-19
- Earliest claimed: 2016-02-03
- Assignees: Conde Systems, Inc.
- Applicants: Conde Systems, Inc.
- Inventors: Paul Andrew Ramsden
- Web page: https://patentgrep.com/patent/US11305570B2

## CPC

- B41M 5/38214: {Structural details, e.g. multilayer systems (composition of individual layers B41M5/42)}
- D06P 5/004: {using subliming dyes}
- B41M 1/30: on organic plastics, horn or similar materials {(recording sheets having a coating to improve ink, dye or pigment receptivity B41M5/50; marking or recording on plastic by irradiation with electromagnetic beams, e.g. laser, B41M5/267)}
- B41M 5/0011: {Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating (after-treatment of prints B41M7/00; printers for treating or overcoating copy materials before, during or after printing B41J11/0015)}
- B41M 5/035: by sublimation or volatilisation of {pre-printed} design {, e.g. sublistatic (B41M5/0256 takes precedence; printing on textiles D06P5/00)}
- B41M 5/0355: {characterised by the macromolecular coating or impregnation used to obtain dye receptive properties}
- B41M 5/0356: {characterised by the inks used for printing the pattern on the temporary support or additives therefor, e.g. dyes, transferable compounds, binders or transfer promoting additives}
- B41M 5/165: characterised by the use of microcapsules; Special solvents for incorporating the ingredients
- B41M 5/38235: {characterised by transferable colour-forming materials}
- B41M 5/5254: {characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers}
- C08J 5/00: Manufacture of articles or shaped materials containing macromolecular substances (manufacture of semi-permeable membranes B01D67/00 - B01D71/00)
- B41M 5/42: Intermediate, {backcoat}, or covering layers {(B41M5/405 takes precedence; multilayer thermal transfer systems in general B41M5/38214)}
- B41M 5/5218: {characterised by inorganic additives, e.g. pigments, clays}
- B41M 2205/02: Dye diffusion thermal transfer printing (D2T2)
- B41M 2205/38: Intermediate layers; Layers between substrate and imaging layer
- B41M: PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING, (correction of typographical errors B41J; processes for applying transfer pictures or the like B44C1/16; fluid media for correction of typographical errors by coating C09D10/00; printing textiles D06P)
- D06P: DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)

## Abstract

It is the object of the present invention to provide a new polymer coating for low temperature plastics and plastic foams that allows for the application of disperse dyes in a sublimation process that preserves the original properties of the underlying plastic substrate. The composition includes an optically clear synthetic organic polymer base holding two layers, a first reflective layer supported by the low temperature plastic substrate that includes IR radiation reflecting additives, and a second layer supported by the first layer having light scattering particulate additives. The disperse dyes utilized in the invention may include additives to absorb IR radiation provided by an external IR source positioned above the disperse dyes causing the dyes to sublimate and diffuse quickly into the light scattering layer. The combination of these layers allows for diffusion of the disperse dye ink into the light scattering layer while protecting the low temperature plastic below.

## Claims

### Claim 1

A decorated low temperature plastic article, comprising:
a. a low-temperature plastic substrate, said substrate comprising the property of unacceptably deforming when exposed to 300 degrees Fahrenheit and 12 pounds per square inch pressure;
b. a first organic polymer coating layer applied to said low-temperature plastic substrate, wherein said first layer includes infrared radiation reflecting particles, said particles including particles having a mean diameter greater than 400 nano-meters;
c. a second organic polymer translucent coating layer applied over said first layer and formulated to disperse visible light hitting said second layer and light being reflected from said first layer, wherein said second layer includes light scattering particles have a mean diameter size less than 400 nano-meters, and wherein said first layer reflects infrared radiation into said second layer and said second layer absorbs said reflected infrared radiation; and,
d. a human discernable image diffused into said pre-applied second layer of polymer coating using a dye sublimation process, wherein said discernable image is comprised of one or more disperse dyes infused into said second layer coating at a molecular level consistent with dye-diffusion.

### Claim 2 (depends on 1)

A decorated plastic article as recited in claim 1, wherein said second coating layer of light scattering particles comprises an average particle size of between 60 nm to 200 nm and are combined with said organic polymer at a loading level of between 10% and 30% by weight of solids.

### Claim 3 (depends on 2)

A decorated plastic article as recited in claim 2, wherein said first coating layer of infrared reflecting particles comprises micronized microspheres held by said organic polymer in a loading volume of less than or equal to 60%.

### Claim 4 (depends on 3)

A decorated plastic article as recited in claim 3, wherein said low-temperature plastic substrate consists of plastics selected from the group consisting of acrylonitrile butadiene styrene plastic, high impact polystyrene plastic, high density polyethylene plastic, polyvinyl chloride plastic, polyethylene terephthalate plastic, and polyethylene terephthalate glycol plastic.

### Claim 5 (depends on 4)

A decorated plastic article as recited in claim 4, wherein said particles held by said second organic polymer coating layer comprise nano-sized particles selected from the group consisting of aluminum oxide, titanium dioxide, zirconium oxide and cerium oxide.

### Claim 6 (depends on 1)

A decorated plastic article as recited in claim 1, wherein said decorated article consists of a maximum of two organic polymer coatings applied over said low-temperature plastic substrate.

### Claim 7 (depends on 1)

A decorated plastic article as recited in claim 1, wherein said low-temperature plastic substrate comprises a plastic foam.

### Claim 8 (depends on 6)

A decorated plastic article as recited in claim 6, wherein said micronized microsphere particles in said first layer comprise glass bubble microspheres.

### Claim 9 (depends on 8)

A decorated plastic article as recited in claim 8, wherein said first and second organic polymer coatings include a base organic polymer mixture selected from the group consisting of acrylic, urethane, polyester, fluorinated polymers, and epoxies.