Polymerizable polar compound, liquid crystal composition and liquid crystal display device
AssigneesJnc Corporation, Jnc Petrochemical Corporation
InventorsTomohiro Yano, Fumitaka Kondo, Hiroki Sago
Life of this patent
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Abstract
A polar compound having high chemical stability, high capability of aligning liquid crystal molecules, high solubility in a liquid crystal composition, and a large voltage holding ratio when the compound is used in a liquid crystal display device; and a composition containing the compound. The compound is represented by formula (1). In formula (1), for example, P1 is a group represented by any one of formulas (1b) to (1i), P2 is a group represented by formula (1d), Sp1 and Sp2 are a single bond, Z1, Z2, Z3, Z4 and Z5 are —COO—, and ring A1, ring A2, ring A3 and ring A4 are 1,4-phenylene:
Claims17
A compound, represented by formula (1):
- wherein, in formula (1),
- a and b are independently 0, 1 or 2, wherein 0≤a+b≤3,
- ring A1, ring A2, ring A3 and ring A4 are independently 1,4-cyclohexylene, 1,4-cyclohexenylene, 1,4-phenylene, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl, tetrahydropyran-2,5-diyl, 1,3-dioxane-2,5-diyl, pyrimidine-2,5-diyl, pyridine-2,5-diyl, fluorene-2,7-diyl, phenanthrene-2,7-diyl, anthracene-2,6-diyl, perhydrocyclopenta[a]phenanthrene-3,17-diyl or 2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydrocyclopenta[a]phenanthrene-3,17-diyl, and in the rings, at least one hydrogen may be replaced by fluorine, chlorine, alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons, alkoxy having 1 to 11 carbons or alkenyloxy having 2 to 11 carbons, and in the groups, at least one hydrogen may be replaced by fluorine or chlorine, and when a is 2, two of ring A1 may be different, and when b is 2, two of ring A4 may be different;
- Z1, Z2, Z3, Z4 and Z5 are independently a single bond or alkylene having 1 to 10 carbons, and in the alkylene, at least one —CH2— may be replaced by —O—, —CO—, —COO—, —OCO— or —OCOO—, and at least one —(CH2)2— may be replaced by —CH═CH— or —C≡C—, and in the groups, at least one hydrogen may be replaced by halogen, in which at least one in Z2, Z3 or Z4 is —COO—, —OCO—, —CH═CHCOO—, —OCOCH═CH—, —CH═CH—, —CH═CHCO— or —COCH═CH—, and when a is 2, two Z*s may be different, and two Z5s may be different;
- Sp1 and Sp2 are independently a single bond or alkylene having 1 to 10 carbons, and in the alkylene, at least one —CH2— may be replaced by —O—, —CO—, —COO—, —OCO— or —OCOO—, and at least one —(CH2)2— may be replaced by —CH═CH— or —C≡C—, and in the groups, at least one hydrogen may be replaced by halogen;
- P1 is a group represented by any one of formulas (1b) to (1i);
- and
- P2 is a group represented by formula (1d);
- wherein, in formulas (1b) to (1i),
- M1 and M2 are independently hydrogen, halogen, alkyl having 1 to 5 carbons, or alkyl having 1 to 5 carbons in which at least one hydrogen is replaced by halogen;
- R2 is hydrogen, halogen or alkyl having 1 to 5 carbons, and in the alkyl, at least one hydrogen may be replaced by halogen, and at least one —CH2— may be replaced by —O—;
- and
- R3, R4 and R5 are independently hydrogen or alkyl having 1 to 15 carbons, and in the alkyl, at least one —CH2— may be replaced by —O— or —S—, and at least one —(CH2)2— may be replaced by —CH═CH— or —C≡C—, and in the groups, at least one hydrogen may be replaced by halogen.
Dependencies are inferred from the claim text.