Composite structure having an inorganic coating adhered thereto and method of making same
AssigneeThe Boeing Company
InventorJames Frank Cordaro
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Abstract
The present disclosure provides a composite structure and associated method for preparing a composite substrate comprising an inorganic coating that is adhered to an organic-based substrate via an adhesion promoting agent comprising a molecule having a urea moiety at one end of the molecule and an alkoxysilane moiety at the other end of the molecule. The use of adhesion promoting agent having at least one of an amine or imine moiety and an alkoxysilane moiety promotes tight adhesion of the inorganic coating to the substrate.
Claims19
A composite structure comprising:
- an epoxy-based matrix, the epoxy-based matrix including chemisorbed water, the chemisorbed water being present by exposing a surface layer of the epoxy-based matrix to water, and wherein the chemisorbed water is disposed only on the surface layer of the epoxy-based matrix;
- an inorganic coating layer disposed overlying said surface layer of the epoxy-based matrix having the chemisorbed water;
- and
- an adhesion promoting agent layer disposed between the epoxy-based matrix and the inorganic coating layer, the adhesion promoting agent layer adhering the inorganic coating to the epoxy-based matrix, the adhesion promoting agent having a following formula:
- wherein X is an alkoxy group having from 1 to 3 carbon atoms;
- and
- n is a number from 1 to 5, and wherein the inorganic coating layer consists of one or more of a) potassium silicate, b) sodium silicate, or c) a combination of potassium silicate or sodium silicate with one or more of a metallic oxide, inorganic pigment, or basic material having a pH greater than 7.
A concrete composite material comprising:
- a concrete matrix;
- a structural member disposed in the concrete matrix, the structural member comprising an epoxy-based matrix including chemisorbed water being present by exposing a surface layer of the epoxy-based matrix to water, and wherein the chemisorbed water is disposed only on the surface layer of the epoxy-based matrix, and an adhesion promoting agent adhering the concrete matrix to said surface layer of the epoxy-based matrix, wherein the adhesion promoting agent has a following formula:
- wherein X is an alkoxy group having from 1 to 3 carbon atoms;
- and
- n is a number from 1 to 5.
A composite structure comprising:
- an epoxy-based matrix, the epoxy-based matrix having chemisorbed water, the chemisorbed water being present by exposing a surface layer of the epoxy-based matrix to water, and the chemisorbed water being disposed only on the surface layer of the epoxy-based matrix;
- an adhesion promoting agent layer overlying said epoxy-based matrix, the adhesion promoting agent having a following formula:
- wherein X is an alkoxy group having from 1 to 3 carbon atoms;
- and n is a number from 1 to 5;
- and
- an inorganic coating layer disposed overlying said adhesion promoting agent layer, the inorganic coating layer consisting of one or more of a) potassium silicate, b) sodium silicate, or c) a combination of potassium silicate or sodium silicate with one or more of a metallic oxide, inorganic pigment, or basic material having a pH greater than 7, and wherein an amount of the inorganic coating removed from the epoxy-based substrate is less than 5% when subjected to ASTM D 3359 Method A.
Dependencies are inferred from the claim text.