# US 11,299,436 B2 · NPK-Si fertilizer, method for production and use thereof

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- Number: US 11,299,436 B2
- Document ID: US11299436B2
- Status: Granted
- Kind: B2
- Application number: 16/765,275
- Filed: 2018-11-20
- Published: 2021-05-13
- Granted: 2022-04-12
- Earliest claimed: 2017-11-20
- Assignees: Elkem ASA
- Applicants: Elkem Asa
- Inventors: Tor Soyland Hansen; Magne Dastol; Vladimir Matychenkov
- Web page: https://patentgrep.com/patent/US11299436B2

## CPC

- C05D 9/00: Other inorganic fertilisers
- C05B 7/00: Fertilisers based essentially on alkali or ammonium orthophosphates (C05B11/00 takes precedence)
- C05B 15/00: Organic phosphatic fertilisers (bone meal C05B17/00)
- C05B 17/00: Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
- C05C 1/00: Ammonium nitrate fertilisers
- C05C 3/00: Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
- C05C 5/02: containing sodium or potassium nitrate
- C05C 9/00: Fertilisers containing urea or urea compounds
- C05D 1/00: Fertilisers containing potassium (C05D7/00 takes precedence)
- C05D 9/02: containing trace elements
- C05D: INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05B: PHOSPHATIC FERTILISERS
- C05C: NITROGENOUS FERTILISERS

## Abstract

The present application relates to a combined NPK-Si fertilizer product comprising a mineral NPK fertilizer, which comprises at least one nutrient compound of nitrogen, phosphorous or potassium, and a particulate amorphous silicon dioxide, wherein the ratio of the mineral NPK fertilizer to the amorphous silicon dioxide is from 10:90 to 90:10, based on the dry weight of the at least one nutrient compound of nitrogen, phosphorous or potassium, and the amorphous silicon dioxide contained in the product. The application also relates to the method of production of the inventive NPK-Si fertilizer.

## Claims

### Claim 1

A combined NPK-Si fertilizer product consisting of
a mineral NPK fertilizer, which comprises nitrogen, phosphorous and potassium, and
a particulate amorphous silicon dioxide,
wherein the ratio of the mineral NPK fertilizer to the amorphous silicon dioxide is from 10:90 to 90:10, based on the dry weight of the nitrogen, phosphorous, and potassium, and the amorphous silicon dioxide contained in the product, and
optionally one or more secondary nutrients, one or more micro nutrients, and/or one or more fillers.

### Claim 2 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the mineral NPK fertilizer contains:
(a) nitrogen (N), in the form of nitrate (NO3−), ammonium (NH4+) and/or urea (CO(NH2)2),
(b) phosphorous (P), in the form of phosphate (PO43−), hydrogen phosphate (HPO42−) and/or dihydrogen phosphate (H2PO4−), and
(c) potassium (K), in the form of potassium salt (K+).

### Claim 3 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the particulate amorphous silicon dioxide is microsilica (silica fume) and/or rice husk ash.

### Claim 4 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the particulate amorphous silicon dioxide is in the form of agglomerated particles, micropellets, pellets or granules.

### Claim 5 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the ratio of the mineral NPK fertilizer to the amorphous silicon dioxide ranges from 20:80 to 80:20, based on the dry weight of nitrogen, phosphorous and potassium, and the amorphous silicon dioxide contained in the product.

### Claim 6 (depends on 1)

The combined NPK-Si fertilizer product according claim 1, wherein the NPK fertilizer contains nutrient compounds of
N, P and K;
N and P;
P and K; and/or
N and K; and/or
in the form of single nutrient fertilizer containing compounds of N, P and/or K,
in addition to the said particulate amorphous silicon dioxide.

### Claim 7 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the NPK-Si fertilizer is in the form of granules, prills, extrudates, pellets or agglomerates.

### Claim 8 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the content of nitrogen nutrient in the NPK fertilizer is up to about 46 weight-% in terms of elemental N.

### Claim 9 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the content of phosphorous nutrient in the NPK fertilizer is up to weight-55% in terms of P2O5.

### Claim 10 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the contents of potassium nutrient in the NPK fertilizer is up to weight-62% in terms of K2O.

### Claim 11 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the optional secondary nutrients are selected from the group consisting of: calcium (Ca), sulphur (S) and magnesium (Mg), and wherein the optional micronutrients are selected from the group consisting of: zinc (Zn), copper (Cu), iron (Fe), boron (B) and molybdenum (Mo).

### Claim 12 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the NPK-Si fertilizer product is in the form of a physical mixture or a blend of at least one particulate mineral NPK fertilizer compound and the particulate amorphous silicon dioxide.

### Claim 13 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the amorphous silicon dioxide is in the form of inclusions in at least one particulate NPK fertilizer or on a surface of at least one particulate NPK fertilizer.

### Claim 14 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the mineral NPK fertilizer is in the form of a compound fertilizer containing nutrient compounds of
N, P and K.

### Claim 15 (depends on 1)

The combined NPK-Si fertilizer product according to claim 1, wherein the NPK-Si fertilizer is in the form of a compound fertilizer containing compounds of N, P and/or K and the particulate amorphous silicon dioxide.

### Claim 16 (depends on 1)

A method for the production of the combined NPK-Si fertilizer product of claim 1, comprising:
(i) adding particulate amorphous silicon dioxide in a liquid stage of the NPK production process forming a slurry, the said liquid stage is subsequent to any acid digestion step of the NPK production process, followed by granulating or prilling; or
(ii) adding particulate amorphous silicon dioxide subsequent a liquid stage of the NPK production process and during an agglomeration process of the production of the mineral NPK fertilizer; or
(iii) dry-mixing at least one preformed particulate NPK fertilizer with a particulate amorphous silicon dioxide, thereby forming a mechanical blend,
wherein the particulate amorphous silicon dioxide is added in an amount to obtain the ratio of mineral NPK fertilizer to the amorphous silicon dioxide of from 10:90 to 90:10 based on the dry weight of the nitrogen, phosphorous and potassium, and the amorphous silicon dioxide contained in the product, thereby producing the combined NPK-Si fertilizer product consisting of
a mineral NPK fertilizer, which comprises nitrogen, phosphorous and potassium, and
a particulate amorphous silicon dioxide,
wherein the ratio of the mineral NPK fertilizer to the amorphous silicon
dioxide is from 10:90 to 90:10, based on the dry weight of the nitrogen, phosphorous, and potassium, and the amorphous silicon dioxide contained in the product, and
optionally one or more secondary nutrients, one or more micro nutrients,
and/or one or more fillers.

### Claim 17 (depends on 16)

The method according to claim 16, wherein in (ii) the particulate amorphous silicon dioxide is in the form of a slurry or dispersion.

### Claim 18 (depends on 17)

The method according to claim 17, wherein the slurry or dispersion is sprayed, or sprinkled during a granulation or prilling process.

### Claim 19 (depends on 16)

The method according to claim 16, wherein the mineral NPK fertilizer contains at least one of the following nutrient compounds:
(a) nitrogen (N), in the form of a nitrate (NO3−), an ammonium (NH4+) and/or urea (CO(NH2)2),
(b) phosphorous (P), in the form of a phosphate (PO43−), hydrogen phosphate (HPO42−) and/or a dihydrogen phosphate (H2PO4−), and
(c) potassium (K), in the form of a potassium salt (K+).

### Claim 20 (depends on 16)

The method according to claim 16, wherein the particulate amorphous silicon dioxide is microsilica (silica fume) and/or rice husk ash.

### Claim 21 (depends on 20)

The method according to claim 20, wherein the particulate amorphous silicon dioxide is in the form of agglomerated particles, micropellets, pellets or granules.

### Claim 22 (depends on 16)

The method according to claim 16, wherein the ratio of the mineral NPK fertilizer to the amorphous silicon dioxide is selected from the group consisting of the following ranges from 20:80 to 80:20, from 30:70 to 70:30, from 40:60 to 60:40 and 50:50, based on the dry weight of the nitrogen, phosphorous and potassium, and the amorphous silicon dioxide contained in the product.

### Claim 23 (depends on 1)

A method for supplying nutrients and/or soil conditioners to agricultural or greenhouse soil, comprising applying the combined NPK-Si fertilizer product according to claim 1 to the agricultural or greenhouse soil.

### Claim 24 (depends on 1)

The method for supplying nutrients and/or soil conditioners to agricultural or greenhouse soil, comprising applying the combined NPK-Si fertilizer according to claim 1 to the agricultural or greenhouse soil, wherein the mineral NPK fertilizer, and the particulate amorphous silicon dioxide, are applied as separate constituents.