# US 11,298,897 B2 · Composite structure having thermoplastic radius filler

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- Number: US 11,298,897 B2
- Document ID: US11298897B2
- Status: Granted
- Kind: B2
- Application number: 16/521,544
- Filed: 2019-07-24
- Published: 2021-01-28
- Granted: 2022-04-12
- Earliest claimed: 2019-07-24
- Assignees: The Boeing Company
- Applicants: The Boeing Company
- Inventors: Devin Knowles; Stanley Stawski
- Web page: https://patentgrep.com/patent/US11298897B2

## CPC

- B29C 70/342: {using isostatic pressure}
- B29C 70/081: {Combinations of fibres of continuous or substantial length and short fibres}
- B29C 70/44: using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
- B29C 70/446: {Moulding structures having an axis of symmetry or at least one channel, e.g. tubular structures, frames}
- B29C 70/549: {Details of caul plates, e.g. materials or shape}
- B29C 70/745: {Filling cavities in the preformed part (for joining B29C70/84)}
- B29D 99/0005: {Producing noodles, i.e. composite gap fillers, characterised by their construction}
- B29D 99/0014: {provided with ridges or ribs, e.g. joined ribs}
- B33Y 80/00: Products made by additive manufacturing
- B29K 2101/12: Thermoplastic materials
- Y02T 50/40: Weight reduction
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- B29D: PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE (making granules B29B9/00; making preforms B29B11/00)
- B33Y: ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION

## Abstract

A method of manufacturing a cured composite structure includes inserting a plurality of radius filler segments into a radius cavity extending along a length of an uncured composite base member to form an uncured structural assembly. The plurality of radius filler segments are placed in end-to-end arrangement within the radius cavity and each having opposing segment ends and being formed of a thermoplastic material. The method additionally includes heating the structural assembly at least to a base member cure temperature that causes the segment ends of end-to-end pairs of the plurality of radius filler segments to fuse together and form a continuous radius filler element that extends along the length of the composite base member. The method also includes allowing the structural assembly to cure to form a cured composite structure.

## Claims

### Claim 1

A method of manufacturing a cured composite structure, comprising:
providing a plurality of radius filler segments, each having breakaway tabs interconnecting the radius filler segments, the breakaway tabs being located at spaced intervals along the length of adjacent pairs of radius filler segments, and extending between side edges of adjacent radius filler segments, and being separable from the radius filler segments;
inserting the plurality of radius filler segments into a radius cavity extending along a length of an uncured composite base member to form an uncured structural assembly, the plurality of radius filler segments being in end-to-end arrangement within the radius cavity and each having opposing segment ends and being formed of a thermoplastic material;
heating the structural assembly at least to a base member cure temperature that is at least as high as the temperature of the thermoplastic material at which the segment ends of end-to-end pairs of the plurality of radius filler segments fuse together and form a continuous radius filler element that extends along the length of the composite base member; and
allowing the structural assembly to cure to form a cured composite structure.

### Claim 2 (depends on 1)

The method of claim 1, wherein the step of heating the structural assembly at least to the base member cure temperature includes:
heating the structural assembly to a temperature that causes the radius filler segments to adhere to the composite base member.

### Claim 3 (depends on 1)

The method of claim 1, wherein:
the radius filler segments each have a length of 3-15 feet; and
the composite base member has a length of greater than 15 feet.

### Claim 4 (depends on 1)

The method of claim 1, wherein the step of inserting the plurality of radius filler segments into the radius cavity includes:
interlocking the segment ends of end-to-end pairs of the plurality of radius filler segments via interlocking features included on the segment ends of the radius filler segments.

### Claim 5 (depends on 1)

The method of claim 1, further comprising:
manufacturing at least one of the radius filler segments by one of three-dimensional printing, selective laser sintering, fused filament fabrication, die extrusion, or injection molding.

### Claim 6 (depends on 1)

The method of claim 1, wherein inserting the plurality of radius filler segments into the radius cavity comprises:
applying location markings on an composite panel indicating locations of the radius filler segments;
placing the radius filler segments on the composite panel in alignment with the location markings to form at least one segment series of end-to-end radius filler segments;
vacuum compacting the radius filler segments to the composite panel to at least partially bond the radius filler segments in position on the composite panel to form an panel subassembly; and
assembling at least one composite base member to the panel subassembly such that the radius filler segments of the segment series are received into the radius cavity of the composite base member to form the structural assembly.

### Claim 7 (depends on 1)

The method of claim 1, wherein the thermoplastic material of the radius filler segments is comprised of at least one of:
acrylonitrile butadiene styrene (ABS), acrylic-styrene-acrylonitrile (ASA), polyethylene terephthalate (PET), polyphenylene sulfide (PPS), polylactic acid (PLA), polycarbonate material, polyether ether ketone (PEEK), polyether ketone ketone (PEKK), copolymeric material.

### Claim 8 (depends on 1)

The method of claim 1, wherein:
the thermoplastic material of the radius filler segments has a Young's modulus that is less than the Young's modulus of the composite base member.

### Claim 9 (depends on 1)

The method of claim 1, wherein:
the thermoplastic material of the radius filler segments has a percent elongation at failure that is greater than the percent elongation at failure of the composite base member.

### Claim 10 (depends on 1)

The method of claim 1, wherein:
the composite base member is comprised of reinforcing fibers embedded in a resin;
the resin of the composite base member comprises one of thermosetting resin and thermoplastic resin;
the thermoplastic resin comprises one of the following:
acrylonitrile butadiene styrene (ABS), acrylic-styrene-acrylonitrile (ASA), polyethylene terephthalate (PET), polyphenylene sulfide (PPS), polylactic acid (PLA), polycarbonate material, polyether ether ketone (PEEK), polyether ketone ketone (PEKK), copolymeric material; acrylics, fluorocarbons, polyamides, polyolefins, polyesters, polycarbonates, polyurethanes, polyetherimides, polyethersulfone, polysulfone, and polyphenyl sulfone;
the thermosetting resin comprises one of the following:
polyurethanes, phenolics, polyimides, sulphonated polymer, a conductive polymer, benzoxazines, bismaleimides, cyanate esthers, polyesters, epoxies, and silsesquioxanes; and
the reinforcing fibers of the composite base member are formed of at least one of plastic, glass, ceramic, carbon, metal or any combination thereof.

### Claim 11

An uncured structural assembly, comprising:
a composite base member having a base member cure temperature and a radius cavity extending along a length of the composite base member;
a plurality of radius filler segments configured to be inserted into the radius cavity in end-to-end arrangement, the plurality of radius filler segments each having opposing segment ends and being homogenous and formed of a thermoplastic material, the plurality of radius filler segments each having breakaway tabs interconnecting the radius filler segments, the breakaway tabs being located at spaced intervals along the length of adjacent pairs of radius filler segments, and extending between side edges of adjacent radius filler segments, and being separable from the radius filler segments;
the thermoplastic material having a temperature at which the segment ends of end-to-end pairs of the plurality of radius filler segments fuse together; and
the base member cure temperature being at least as high as the temperature at which the segment ends of the radius filler segments fuse together.

### Claim 12 (depends on 11)

The uncured structural assembly of claim 11, wherein:
the segment ends each have interlocking features configured to interlock end-to-end pairs of the plurality of radius filler segments.

### Claim 13 (depends on 11)

The uncured structural assembly of claim 11, wherein the thermoplastic material of the radius filler segments is comprised of at least one of:
acrylonitrile butadiene styrene (ABS), acrylic-styrene-acrylonitrile (ASA), polyethylene terephthalate (PET), polyphenylene sulfide (PPS), polylactic acid (PLA), polycarbonate material, polyether ether ketone (PEEK), polyether ketone ketone (PEKK), copolymeric material.

### Claim 14 (depends on 11)

The uncured structural assembly of claim 11, wherein:
the base member is comprised of reinforcing fibers embedded in resin;
the resin of the composite base member comprises one of thermosetting resin and thermoplastic resin;
the thermoplastic resin comprises one of the following:
acrylonitrile butadiene styrene (ABS), acrylic-styrene-acrylonitrile (ASA), polyethylene terephthalate (PET), polyphenylene sulfide (PPS), polylactic acid (PLA), polycarbonate material, polyether ether ketone (PEEK), polyether ketone ketone (PEKK), copolymeric material; acrylics, fluorocarbons, polyamides, polyolefins, polyesters, polycarbonates, polyurethanes, polyetherimides, polyethersulfone, polysulfone, and polyphenylsulfone; and
the thermosetting resin comprises one of the following:
polyurethanes, phenolics, polyimides, sulphonated polymer, a conductive polymer, benzoxazines, bismaleimides, cyanate esthers, polyesters, epoxies, and silsesquioxanes; and
the reinforcing fibers of the composite base member are formed of at least one of plastic, glass, ceramic, carbon, metal or any combination thereof.

### Claim 15 (depends on 11)

The uncured structural assembly of claim 11, wherein:
the temperature at which the segment ends fuse together is the glass transition temperature of the thermoplastic material.

### Claim 16 (depends on 11)

The uncured structural assembly of claim 11, wherein:
the radius filler segments each have a length of 3-15 feet; and
the composite base member has a length of greater than 15 feet.

### Claim 17 (depends on 11)

The uncured structural assembly of claim 11, wherein:
each breakaway tab has a notch extending across a width of the breakaway tab, and located proximate an intersection of the breakaway tab with one of the radius filler segments interconnected by the breakaway tab.

### Claim 18 (depends on 11)

The uncured structural assembly of claim 11, wherein:
the thermoplastic material of the radius filler segments contains fibers.

### Claim 19 (depends on 12)

The uncured structural assembly of claim 12, wherein the interlocking features comprise:
a tab on the segment end of at least one of the radius filler segments, and a recess on the segment end of another one of the radius filler segments, the tab is configured to nest within the recess.

### Claim 20 (depends on 17)

The uncured structural assembly of claim 17, wherein:
the tab and the recess each have a dovetail configuration.
