# US 11,298,869 B2 · Method and apparatus for producing a high aspect ratio nanostructured foil by extrusion coating or extrusion casting

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- Number: US 11,298,869 B2
- Document ID: US11298869B2
- Status: Granted
- Kind: B2
- Application number: 17/123,427
- Filed: 2020-12-16
- Published: 2021-05-06
- Granted: 2022-04-12
- Earliest claimed: 2014-03-24
- Assignees: Inmold A/S; Danapak Flexibles A/S
- Applicants: Inmold A/S; Danapak Flexibles A/S
- Inventors: Henrik Pranov; Maria Matschuk; Sanne Norup Westad; Peter Lass Johansen; Ole Brodsgard
- Web page: https://patentgrep.com/patent/US11298869B2

## CPC

- B29C 59/046: {for layered or coated substantially flat surfaces}
- B05D 1/265: {Extrusion coatings}
- B29C 43/222: {characterised by the shape of the surface}
- B29C 43/46: Rollers
- B29C 48/154: Coating solid articles, i.e. non-hollow articles
- B29C 48/251: {Design of extruder parts, e.g. by modelling based on mathematical theories or experiments}
- B29C 59/022: {characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor}
- B29C 2043/461: {the rollers having specific surface features}
- B29C 2059/023: {Microembossing}
- B29K 2101/12: Thermoplastic materials
- B29K 2105/20: Inserts
- B29K 2909/02: Ceramics
- B29K 2995/004: Semi-crystalline
- B29K 2995/0093: hydrophobic
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- B05D: PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL (conveying articles or workpieces through baths of liquid B65G, e.g. B65G49/02)
- B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS

## Abstract

A solid nano- or micro-structured thermoplastic foil including a nano- or micro-structured surface area is produced by providing an extrusion casting roller for an industrial polymer extrusion casting process using a thermoplastic material, applying a nano- or micro-structured surface on the extrusion casting roller, maintaining a temperature of the casting roller below a solidification temperature of the thermoplastic material while the casting roller and the counter roller are rotating, and continuously applying a melt of the thermoplastic material between a counter roller and the casting roller while the casting roller and the counter roller are rotating. A rotational velocity of the casting roller may be 10 meters/minute. The melt of the thermoplastic material is moved between the casting roller and the counter roller while the rollers are rolling, and the melt of the thermoplastic material is solidified upon contact with the casting roller to form the thermoplastic foil.

## Claims

### Claim 1

A method for producing a nano- or micro-structured thermoplastic polymer coating on a carrier foil comprising at least one nano- or micro-structured surface area, said method comprising:
providing an extrusion coating roller for an industrial polymer extrusion coating process using a thermoplastic material;
applying a nano- or micro-structured surface on the said extrusion coating roller thereby forming a nano- or micro-structured extrusion coating roller;
maintaining a temperature of the said nano- or micro-structured extrusion coating roller below a solidification temperature of the said thermoplastic material;
moving the carrier foil between a rotating nano- or micro-structured extrusion coating roller and a rotating counter pressure roller at a given velocity corresponding to a rotational velocity of the rotating nano- or micro-structured extrusion coating roller, wherein the said velocity of the carrier foil and the rotational velocity of the said nano- or micro-structured extrusion coating roller is higher than 10 meters per minute; and
extrusion coating a thermoplastic polymer material onto said moving carrier foil to form a solid nano- or micro-structured thermoplastic polymer material coating on said carrier foil, wherein the extrusion coating comprises continuously applying an extruded melt of said thermoplastic polymer material between the said moving carrier foil and the said rotating nano- or micro-structured extrusion roller, wherein said melt of said thermoplastic polymer material is solidified upon contact with said nano- or micro-structured extrusion coating roller maintained at a second temperature below the solidification temperature of the said melt of said thermoplastic polymer material.

### Claim 2 (depends on 1)

The method according to claim 1, wherein an aspect ratio of the said solid nano- or micro-structured thermoplastic polymer coating is above 2.

### Claim 3 (depends on 1)

The method according to claim 1, wherein nano- or micro-structures are produced on both sides of a cast foil by using both a nano- or micro-structured extrusion roller and a nano- or micro-structured counter roller.

### Claim 4 (depends on 1)

The method according to claim 1, wherein the said nano- or micro-structured surface is applied by mounting nano- or micro-structured shims on the said extrusion coating roller.

### Claim 5 (depends on 1)

The method according to claim 1, wherein a nano- or micro-structured area of the said carrier foil is spatially continuous over a length higher than a circumference of the said nano- or micro-structured extrusion coating roller.

### Claim 6 (depends on 1)

The method according to claim 1, wherein seam lines between individual nano- or micro-structured areas have a width of less than 50 μm.

### Claim 7 (depends on 1)

The method according to claim 1, wherein the said nano- or micro-structured thermoplastic coating on said carrier foil provides a functionality of increased contact to water angle of at least 30 degrees relative to an otherwise identical, but non-structured thermoplastic coating.

### Claim 8 (depends on 1)

The method according to claim 1, wherein the carrier foil is subsequently metalized to form isolated metal domains on top of the said nano- or micro-structured thermoplastic coating with a lateral size and thickness below 1000 nm.

### Claim 9 (depends on 1)

The method according to claim 1, wherein the said melt of said thermoplastic polymer material is kept in protected atmosphere to maintain chemical properties of the thermoplastic material.