# US 11,297,838 B2 · Pesticidal compositions and methods

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- Number: US 11,297,838 B2
- Document ID: US11297838B2
- Status: Granted
- Kind: B2
- Application number: 17/263,924
- Filed: 2019-12-12
- Published: 2021-09-16
- Granted: 2022-04-12
- Earliest claimed: 2018-12-26
- Assignees: Corteva Agriscience LLC
- Applicants: Corteva Agriscience LLC
- Inventors: Natalie C. Giampietro; David Demeter; Lindsey G. Horty; Gary D. Crouse; Thomas C. Sparks
- Web page: https://patentgrep.com/patent/US11297838B2

## CPC

- A01N 47/18: containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
- A01N 47/22: O-Aryl or S-Aryl esters thereof
- A61K 31/427: not condensed and containing further heterocyclic rings
- A61P 33/14: Ectoparasiticides, e.g. scabicides
- C07D 403/12: linked by a chain containing hetero atoms as chain links
- C07D 417/12: linked by a chain containing hetero atoms as chain links
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D)
- A61P: SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- C07D: HETEROCYCLIC COMPOUNDS (macromolecular compounds C08)

## Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the structure of Formula A.

## Claims

### Claim 1

A molecule having the structure of Formula A:
wherein:
(A) Ar1 is phenyl or substituted phenyl wherein said substituted phenyl has one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), SS(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)NRxRy, (C1-C8 alkyl)NRxRy, C(═O)C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, or S(═O)nNRxRy, or (Het-1),
wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, phenoxy, and (Het-1) substituent may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)NRxRy, (C1-C8 alkyl)NRxRy, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)OC1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(═O)nNRxRy, or (Het-1);
(B) Het is triazolyl;
(C) Ar2 is phenyl or substituted phenyl wherein said substituted phenyl has one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)NRxRy, (C1-C8 alkyl)NRxRy, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(═O)nNRxRy, or (Het-1),
wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, phenoxy, and (Het-1) substituent may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)NRxRy, (C1-C8 alkyl)NRxRy, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(═O)nNRxRy, or (Het-1);
(D) L is linker selected from
(1) a bond,
(2) —CR4R5—CR6R7—, or
(3) —CR4=CR6—,
wherein each of R4, R5, R6, and R7 is selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, C2-C8 haloalkynyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C3-C8 cycloalkenyl, C3-C8 halocycloalkenyl, C(═O)(C1-C6 alkyl), C(═O)O(C1-C6 alkyl), C(═O)(C3-C6 cycloalkyl), C(═O)O(C3-C6 cycloalkyl), C(═O)(C2-C6 alkenyl), C(═O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(═O)n(C1-C6 alkyl), C(═O)(C1-C6 alkyl)C(═O)O(C1-C6 alkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C3-C8 cycloalkyl), S(═O)n(C1-C8 haloalkyl), S(═O)n(C3-C8 halocycloalkyl), phenyl, or phenoxy;
(E) R4 and R6 together can optionally form a 3- to 7-membered saturated or unsaturated ring which may contain C═O, C═S, N, S or O, and is optionally substituted with H, OH, F, Cl, Br, I, CN, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 hydroxyalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 hydroxycycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C3-C6 hydroxycycloalkoxy, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyl, C3-C6 cycloalkenyl, C2-C6 alkynyl, C3-C6 cycloalkynyl, S(═O)n(C1-C6 alkyl), S(═O)n(C1-C6 haloalkyl), OSO2(C1-C6 alkyl), OSO2(C1-C6 haloalkyl), C(═O)H, C(═O)OH, C(═O)NRxRy, (C1-C6 alkyl)NRxRy, C(═O)(C1-C6 alkyl), C(═O)O(C1-C6 alkyl), C(═O)(C1-C6 haloalkyl), C(═O)O(C1-C6 haloalkyl), C(═O)(C3-C6 cycloalkyl), C(═O)O(C3-C6 cycloalkyl), C(═O)(C2-C6 alkenyl), C(═O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(═O)n(C1-C6 alkyl), C(═O)(C1-C6 alkyl)C(═O)O(C1-C6 alkyl), phenyl, phenoxy, and Het-1;
(F) Q1 is selected from O or S;
(G) Q2 is selected from O or S;
(H) R1 is selected from (J), H, C1-C8 alkyl, C3-C8 cycloalkyl, C2-C8 alkenyl, C2-C8 alkynyl, C(═O)(C1-C8 alkyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, C(═O)(Het-1), (Het-1), (C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-O—C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-O—C(═O)NRxRy, (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(═O)(Het-1), (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)N(Ry)C(═O)OH, (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)N(Rx)(Ry), (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)N(Ry)C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)(N(Ry)C(═O)O—(C1-C8 alkyl)C(═O)OH, (C1-C8 alkyl)-C(═O)(Het-1)C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C3-C8 cycloalkyl), (C1-C8 alkyl)-OC(═O)-(Het-1), (C1-C8 alkyl)-OC(═O)—(C1-C8 alkyl)N(Rx)C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-NRxRy, (C1-C8 alkyl)-S-(Het-1), (C1-C8 alkyl)S(═O)n(Het-1), or (C1-C8 alkyl)-O-(Het-1),
wherein each alkyl, cycloalkyl, phenyl, and (Het-1) are optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)H, C(═O)OH, C(═O)NRxRy, (C1-C8 alkyl)NRxRy, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(═O)nNRxRy, or (Het-1);
(I) R2 is selected from (J), H, OH, SH, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)H, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, C(═O)(Het-1), (Het-1), (C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-O—C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-O—C(═O)NRxRy, (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(═O)(Het-1), (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)N(Ry)C(═O)OH, (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)N(Rx)(Ry), (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)N(Ry)C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-C(═O)N(Rx)(C1-C8 alkyl)(N(Ry)C(═O)O—(C1-C8 alkyl)C(═O)OH, (C1-C8 alkyl)-C(═O)(Het-1)C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C3-C8 cycloalkyl), (C1-C8 alkyl)-OC(═O)-(Het-1), (C1-C8 alkyl)-OC(═O)—(C1-C8 alkyl)N(Rx)C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-NRxRy, (C1-C8 alkyl)-S-(Het-1), (C1-C8 alkyl)S(═O)n(Het-1), or (C1-C8 alkyl)-O-(Het-1),
wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, cycloalkoxy, halocycloalkoxy, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, and (Het-1), are optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)H, C(═O)OH, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, halophenyl, phenoxy, and (Het-1);
(J) R1 and R2 may be a 1- to 4-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and together with (Q2)(C)(N) forms a 4- to 7-membered cyclic structure, wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)H, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, substituted phenyl, phenoxy, or (Het-1);
(K) R3 is selected from C3-C8 cycloalkyl, phenyl, (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, (C2-C8 alkenyl)-O-phenyl, (Het-1), (C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-O-(Het-1),
wherein the C3-C8 cycloalkyl, phenyl, (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, (C2-C8 alkenyl)-O-phenyl, (Het-1), (C1-C8 alkyl)-(Het-1), or (C1-C8 alkyl)-O-(Het-1) may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)O(C1-C8 haloalkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(═O)nNRxRy, or (Het-1) or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(═O)n(C1-C6 alkyl), S(═O)n(C1-C6 haloalkyl), phenyl, and oxo;
(L) Rx and Ry are independently selected from H, OH, SH, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)H, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, C(═O)(Het-1), (Het-1), (C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-O—C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-C(═O)(Het-1), (C1-C8 alkyl)-C(═O)(Het-1)C(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)O—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C1-C8 alkyl), (C1-C8 alkyl)-OC(═O)—(C3-C8 cycloalkyl), (C1-C8 alkyl)-OC(═O)-(Het-1), (C1-C8 alkyl)-S-(Het-1), (C1-C8 alkyl)S(═O)n(Het-1), or (C1-C8 alkyl)-O-(Het-1),
wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, cycloalkoxy, halocycloalkoxy, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, and (Het-1), are optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)H, C(═O)OH, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, halophenyl, phenoxy, and (Het-1),
or Rx and Ry together can optionally form a 5- to 7-membered saturated or unsaturated cyclic group which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and where said cyclic group may be substituted with H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, substituted phenyl, phenoxy, and (Het-1);
(M) (Het-1) is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur or oxygen, wherein said heterocyclic ring may also be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)NRxRy, (C1-C8 alkyl)NRxRy, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)O(C1-C8 haloalkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, and phenoxy,
wherein each alkyl, cycloalkyl, alkoxy, alkenyl, alkynyl, phenyl, and phenoxy may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(═O)n(C3-C8 cycloalkyl), S(═O)n(C3-C8 halocycloalkyl), S(═O)n(C1-C8 alkyl), S(═O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(═O)H, C(═O)NRxRy, (C1-C8 alkyl)NRxRy, C(═O)(C1-C8 alkyl), C(═O)O(C1-C8 alkyl), C(═O)(C1-C8 haloalkyl), C(═O)O(C1-C8 haloalkyl), C(═O)(C3-C8 cycloalkyl), C(═O)O(C3-C8 cycloalkyl), C(═O)(C2-C8 alkenyl), C(═O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(═O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)(C1-C8 alkyl), (C1-C8 alkyl)OC(═O)O(C1-C8 alkyl), C(═O)(C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)O(C1-C8 alkyl), (C1-C8 alkyl)C(═O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, and phenoxy; and
(N) n is each individually 0, 1, or 2.

### Claim 2 (depends on 1)

The molecule of claim 1, having the structure of Formula One, Formula Two, or Formula Three:
wherein:
(A) Ar1 is a phenyl or substituted phenyl having one or more substituents independently selected from C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy and C1-C6 haloalkoxy;
(B) Het is triazolyl;
(C) Ar2 is a phenyl or a substituted phenyl having one or more substituents independently selected from F, Cl, Br, I, CN, NO2, NRxRy, C1-C6 alkyl, C1-C6 alkoxy, and C1-C6 haloalkyl;
(D) Each R4, R5, R6, and R7 is selected from a H, F, Cl, Br, I, CN, oxo, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkenyl, C3-C6 halocycloalkyl, and phenyl;
(E) R1 is selected from (J), H, C1-C6 alkyl or C2-C6 alkenyl, wherein said alkyl or alkenyl is optionally substituted with a C3-C6 cycloalkyl or C1-C6 alkoxy;
(F) R2 is selected from (J), H, OH, SH, C1-C6 alkyl or C2-C6 alkenyl, wherein said alkyl or alkenyl is optionally substituted with a C3-C6 cycloalkyl or C1-C6 alkoxy;
(G) R3 is phenyl or (Het-1), wherein the phenyl or (Het-1) may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C8 alkyl)O(C1-C8 haloalkyl), (C1-C6 alkyl)S(═O)n(C1-C6 alkyl), C1-C6 alkoxy, C1-C6 haloalkoxy, S(═O)n(C1-C6 alkyl), S(═O)n(C1-C6 haloalkyl), phenyl, and oxo or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(═O)n(C1-C6 alkyl), and S(═O)n(C1-C6 haloalkyl);
(H) Rx and Ry are independently selected from H, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, and phenyl;
(I) (Het-1) is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur or oxygen, wherein said heterocyclic ring may also be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(═O)n(C1-C6 alkyl), S(═O)n(C1-C6 haloalkyl), phenyl, and oxo; and
(J) R1 and R2 may be a 1- to 4-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and together with (Q2)(C)(N) forms a 4- to 7-membered cyclic structure, wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(═O)n(C1-C6 alkyl), S(═O)n(C1-C6 haloalkyl), phenyl, and oxo.

### Claim 3 (depends on 1)

The molecule of claim 1, wherein Ar1 is a substituted phenyl having one or more substituents independently selected from OCF3, OCF2CF3, and CF3.

### Claim 4 (depends on 1)

The molecule of claim 1, wherein Het is 1,2,4-triazolyl.

### Claim 5 (depends on 1)

The molecule of claim 1, wherein Ar2 is a phenyl.

### Claim 6 (depends on 1)

The molecule of claim 1, wherein Ar2 is a substituted phenyl having one or more substituents independently selected from H, F, Cl, Br, I, CN, C1-C6 alkyl, and C1-C6 alkoxy.

### Claim 7 (depends on 1)

The molecule of claim 1, wherein R1 and R2 together form a 5-membered ring containing one or two C═O, and such ring is optionally substituted with H, OH, F, Cl, Br, I, CN, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, phenyl or phenoxy.

### Claim 8 (depends on 1)

The molecule of claim 1, wherein each of R4, R5, R6, and R7 is independently H, F, Cl, or a C1-C6 alkyl.

### Claim 9 (depends on 1)

The molecule of claim 1, wherein R3 is a substituted phenyl with one or more H, F, Cl, Br, I, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, (C1-C6 alkyl)O(C1-C6 alkyl), C1-C6 alkoxy, C1-C6 haloalkoxy, or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(═O)n(C1-C6 alkyl), and S(═O)n(C1-C6 haloalkyl).

### Claim 10 (depends on 1)

A molecule that is a pesticidally acceptable acid addition salt, a salt derivative, a solvate, or an ester derivative, of a molecule according to claim 1.

### Claim 11 (depends on 1)

A molecule according to claim 1 wherein at least one H is 2H or at least one C is 14C.

### Claim 12 (depends on 1)

A composition comprising a molecule according to claim 1 and at least one other compound having insecticidal, herbicidal, acaricidal, nematicidal, or fungicidal activity.

### Claim 13 (depends on 1)

A composition comprising a molecule according to claim 1 and a seed.

### Claim 14 (depends on 1)

The molecule of claim 1 having a structure selected from compounds listed in Table 1
TABLE 1
Structures for Compounds
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
A11
A12
A13
A14
A15
A16
A17
A18
A19
A20
A21
A22
A23
A24
A25
A26
A27
A28
A29
A30
A31
A32
A33
A34
A35
A36
A37
A38
A39
A40
A41
A42
A43
A44
A45
A46
A47
A48
A49
A50
A51
A52
A53
A54
A55
.

### Claim 15 (depends on 1)

A process to apply a molecule according to claim 1 comprising, applying a molecule according to claim 1, to an area to control a pest, in an amount sufficient to control such pest.

### Claim 16 (depends on 15)

A process according to claim 15, wherein said pest is beet armyworm (BAW), cabbage looper (CL), or yellow fever mosquito (YFM).

### Claim 17 (depends on 1)

A process comprising applying a molecule according to claim 1 to a genetically modified plant, or genetically-modified seed, which has been genetically modified to express one or more specialized traits.

### Claim 18 (depends on 1)

A process comprising: orally administering; or topically applying; a molecule according to claim 1, to a non-human animal, to control endoparasites, ectoparasites, or both.