Chemisorption of carbonyls from liquid phase hydrocarbons using solid sodium bisulfite

Abstract

Disclosed are methods and systems for removing reactive carbonyl monomers which can polymerize to produce red oil. In an embodiment the method may include cracking a hydrocarbon stream in a fluidized catalytic cracker to produce a cracked hydrocarbon stream comprising carbonyl compounds; separating hydrocarbon components from the cracked hydrocarbon stream in a debutanizer column to form a debutanizer overhead LPG stream comprising the carbonyl compounds; introducing the debutanizer LPG overhead stream into a carbonyl removal unit comprising a metal bisulfite bed; reacting the carbonyl compounds in the debutanizer overhead LPG stream to form a carbonyl adduct with the metal bisulfite; and withdrawing a first LPG product stream from the carbonyl removal unit.

Dependencies are inferred from the claim text.