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US 11,279,663 B2Granted
Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock
AssigneeSaudi Arabian Oil Company
InventorsOmer Refa Koseoglu, Robert Hodgkins
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Abstract
Provided here are systems and methods that integrate a hydrodearylation process and a transalkylation process into an aromatic recovery complex. Various other embodiments may be disclosed and claimed.
Claims19
A process for recovery of alkyl mono-aromatic compounds and benzene, the process comprising the steps of:
- supplying an aromatic bottoms stream comprising C11+ aromatic compounds from an aromatic recovery complex to a hydrodearylation reactor with a hydrodearylation catalyst;
- producing from the hydrodearylation reactor by processing the C11+ aromatic compounds under hydrodearylation conditions a hydrodearylated liquid product stream comprising benzene, toluene, and C8+ compounds;
- supplying a portion of the hydrodearylated liquid product stream to a transalkylation reactor to react the hydrodearylated liquid product stream in the presence of a transalkylation catalyst to produce a transalkylation product stream including benzene, C8+ aromatics including ethylbenzene and xylenes, and toluene;
- separating in a first separation column the transalkylation product stream into three fractions including a first overhead stream comprising benzene, a first bottoms stream comprising C8+ aromatics including ethylbenzene and xylenes, and a side-cut stream comprising toluene;
- recycling toluene from the side-cut stream comprising toluene to the transalkylation reactor;
- and
- producing para-xylene from the first bottoms stream comprising C8+ aromatics including ethylbenzene and xylenes.
4 more elements
Dependencies are inferred from the claim text.