Polymerizable compound and optically anisotropic object
AssigneeDIC Corporation
InventorsMasahiro Horiguchi, Sayaka Nose, Akihiro Koiso
Life of this patent
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Abstract
The present invention aims to provide a polymerizable compound that has high storage stability without causing crystal precipitation when added to a polymerizable composition and to provide a polymerizable composition containing the polymerizable compound. A polymer film produced by polymerization of the polymerizable composition has a low haze, high thickness uniformity, low occurrence of nonuniform orientation, high surface hardness, high adhesiveness, and good appearances and fewer orientation defects even after ultraviolet irradiation. The present invention also aims to provide a polymer produced by polymerization of the polymerizable composition and an optically anisotropic body produced from the polymer.
Claims7
A reverse dispersion compound represented by formula (I-z2-A-1),
- wherein Mz denotes a group selected from the following formulae (M-z-1) to (M-z-2)
- Rz2 denotes a hydrogen atom,
- Wz1 denotes the following formula (W-a-5),
- in the formula (W-a-5), s is an integer in the range of 0 to 4,
- LWz denotes a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfuranyl group, a nitro group, a cyano group, an isocyano group, an amino group, a hydroxy group, a mercapto group, a methylamino group, a dimethylamino group, a diethylamino group, a diisopropylamino group, a trimethylsilyl group, a dimethylsilyl group, a thioisocyano group, a linear alkyl group having 1 to 20 carbon atoms with one —CH2— or nonadjacent two or more —CH2—'s optionally independently substituted by —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, or —NH—CO—, or a branched alkyl group having 3 to 20 carbon atoms with one —CH2— or nonadjacent two or more —CH2—'s optionally independently substituted by —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, or —NH—CO—, and any hydrogen atom of the alkyl group may be substituted by a fluorine atom, and a plurality of LWz's, if present at all, may be the same or different,
- Wz21 denotes a group selected from a linear alkyl group having 1 to 20 carbon atoms with one —CH2— or nonadjacent two or more —CH2—'s optionally independently substituted by —O—, or a branched alkyl group having 3 to 20 carbon atoms with one —CH2— or nonadjacent two or more —CH2—'s optionally independently substituted by —O—,
- Pz2 and Pz3 independently denote a group selected from the formulae (P-1) to (P-20),
- Sz2 and Sz3 independently denote an alkylene group having 1 to 20 carbon atoms with one —CH2— or nonadjacent two or more —CH2—'s optionally independently substituted by —O—, —COO—, —OCO—, —OCO—O—, —CO—NH—, —NH—CO—, —CH═CH—, or —C≡C—, if present at all, may be the same or different,
- Xz2 and Xz3 independently denote —O—, —S—, —OCH2—, —CH2O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —SCH2—, —CH2S—, —CF2O—, —OCF2—, —CF2S—, —SCF2—, —CH═CH—COO—, —CH═CH—OCO—, —COO—CH═CH—, —OCO—CH═CH—, —COO—CH2CH2—, —OCO—CH2CH2—, —CH2CH2—COO—, —CH2CH2—OCO—, —COO—CH2—, —OCO—CH2—, —CH2—COO—, —CH2—OCO—, —CH═CH—, —N═N—, —CH═N—N═CH—, —CF═CF—, —C≡C—, or a single bond, a plurality of X's, if present at all, may be the same or different, provided that Pz2-(Sz2-Xz2)kz- and Pz3-(Sz3-Xz3)kz- have no —O—O— bond,
- Az311 and Az421 independently denote a 1,4-phenylene group, the group may be unsubstituted or substituted by one or more substituents Lz11's, Lz11 denotes a fluorine atom, a chlorine atom, a linear alkyl group having 1 to 20 carbon atoms with one —CH2— or nonadjacent two or more —CH2—'s optionally independently substituted by —O—, —CO—, —COO—, or —OCO—, any hydrogen atom of the alkyl group may be substituted by a fluorine atom, or a branched alkyl group having 3 to 20 carbon atoms with one —CH2— or nonadjacent two or more —CH2—'s optionally independently substituted by —O—, —CO—, —COO—, or —OCO—, any hydrogen atom of the alkyl group may be substituted by a fluorine atom,
- Az321 and Az411 denote a 1,4-cyclohexylene group,
- Zz311 and Zz421 independently denote —OCH2—, —CH2O—, —COO—, or —OCO—,
- Zz321 and Zz411 independently denote —OCH2— or —CH2O—,
- kz is an integer in the range of 0 to 8.
Dependencies are inferred from the claim text.