Flexible substrates comprising curable compositions containing acetoacetylated resins

An article of manufacture comprising at least one flexible substrate coated with at least one curable composition comprising:

• I. a first component (I) comprising at least one resin having at least one functional group selected from the group consisting of β-ketoester and malonate functional groups, wherein the resin is a either an amorphous polyester, a semi-crystalline polyester or a polyether, or a combination thereof, wherein Component (I) is at least one acetoacetate functional polyester comprising the residues of:
• a. a hydroxyl component comprising:
• i. at least one diol in an amount ranging from 0 to 100 mole % or 50 to 100 mole %, based on the total moles of (i) and (ii) equaling 100 mole %;
• and
• ii. at least one polyol in an amount ranging from 0 to 100 mole % or 0 to 50 mole %, based on the total moles of (i) and (ii) equaling 100 mole %;
• b. at least one carboxyl component comprising a polycarboxylic acid compound, a derivative of a polycarboxylic acid compound, or a combination thereof;
• and
• c. at least one compound selected from an alkyl acetoacetate, a diketene, or a combination thereof,
• II. a second component (II) comprising at least one curing agent having at least one aldehyde functional group, and
• III. a third component (III) comprising at least one compound having amine functionality, salts thereof, or combinations thereof.