Microporous membrane lithium ion secondary battery and method of producing the microporous membrane
AssigneeToray Industries, Inc.
InventorTakeshi Ishihara
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AssigneeToray Industries, Inc.
InventorTakeshi Ishihara
Estimating the term…
A method suppresses membrane thickness variation and air resistance variation after a compression at 60° C. or 80° C. Stretching is performed at least twice in at least different axial directions before the extraction of the solvent, and at the same time, at least one of (i) and (ii) is satisfied. (i) The step (c) is a first stretching step of stretching the sheet-shaped product at least once in a sheet transport direction (MD direction) and at least once in a sheet width direction (TD direction) individually, and the MD stretching magnification and the TD stretching magnification in the step (c) satisfy (TD stretching magnification≥MD stretching magnification−2). (ii) The stretching temperature (T1) of a first axial stretching performed firstly in the step (c) and the maximal stretching temperature (T2) of a second stretching performed after the first axial stretching satisfy (T1−T2≥0).
A microporous membrane, wherein average membrane thickness is 15 μm or less, air resistance is 400 seconds or less, pin puncture strength corresponding to a membrane thickness of 12 μm is 4000 mN or more, and air resistance variation (60° C.) after a pressurization treatment under conditions of 60° C., 4 MPa, and 10 minutes is 148% or less:
Dependencies are inferred from the claim text.