Heat shrinkable film composition comprising polyethyleneterephtalate resin and polyester based copolymer, and heat shrinkable film
AssigneeSK Chemicals Co., Ltd.
InventorsSeol-Hee Lim, Sung-Gi Kim
Life of this patent
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Abstract
A composition for forming a heat shrinkable film includes a polyethylene terephthalate (PET) resin having an inherent viscosity of 0.50 to 1.2 dl/g, and a polyester based copolymer including a dicarboxylic acid-derived residue including a residue derived from an aromatic dicarboxylic acid and a diol-derived residue including a residue derived from 4-(hydroxymethyl)cyclohexylmethyl 4′-(hydroxymethyl)cyclohexane carboxylate represented by the following Chemical Formula 1 and a residue derived from 4,4-(oxybis(methylene)bis)cyclohexane methanol represented by the following Chemical Formula 2.
Claims1
A heat shrinkable film, made by a method comprising:
- extruding a composition comprising:
- a polyethylene terephthalate (PET) resin having an inherent viscosity of 0.50 to 1.2dl/g;
- and
- a polyester based copolymer including a dicarboxylic acid-derived residue including a residue derived from an aromatic dicarboxylic acid;
- and
- a diol-derived residue including a residue derived from 4-(hydroxymethyl)cyclohexylmethyl 4′-(hydroxymethyl)cyclohexane carboxylate represented by the following Chemical Formula 1, a residue derived from 4,4-(oxybis(methylene)bis) cyclohexane methanol represented by the following Chemical Formula 2, and a residue derived from 1,4-cyclohexane dimethanol, to draw the extruded product,
- wherein the polyester based copolymer is prepared by reacting the dicarboxylic acid-derived residue and the diol-derived residue to perform an esterification reaction and a polycondensation reaction,
- wherein a total content of 4-(hydroxymethyl)cyclohexylmethyl 4′-(hydroxymethyl)cyclohexane carboxylate and the residue derived from 4,4-(oxybis(methylene)bis) cyclohexane methanol is 2 to 17 mol % of the entire diol,
- wherein the 4-(hydroxymethyl)cyclohexylmethyl 4′ (hydroxymethyl)cyclohexane carboxylate, the 4,4-(oxybis(methylene)bis) cyclohexane methanol, and the 1,4-cyclohexane dimethanol are present in an amount of 20 to 30 mol % relative to 100 mol % of the dicarboxylic acid, and
- wherein a temperature of a feeder of an extruder is lower than a temperature of a die, wherein the temperature of the die is between 270 and 275° C.
Dependencies are inferred from the claim text.