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US 11,235,306 B2Granted
Phenothiazine based crosslinked polymer and methods thereof
AssigneeKing Fahd University of Petroleum and Minerals
InventorsOthman Charles Sadeq Al Hamouz, Mahmoud Mohamed Abdelnaby
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Abstract
Crosslinked polymers made up of polymerized units of phenothiazine, pyrrole, and aldehyde. The crosslinked polymers are porous with a BET surface area in the range of 300-600 m2/g. A method of synthesizing the crosslinked polymers is described. Processes for using the crosslinked polymers as adsorbent materials for adsorbing gases (e.g. CO2 capturing), and separating fluid mixtures under dry and wet conditions are also introduced.
Claims20
A crosslinked polymer, comprising reacted units of:
- a phenothiazine monomer of formula (I)
- or a salt thereof, a solvate thereof, a tautomer thereof a stereoisomer thereof, or a mixture thereof;
- a pyrrole monomer of formula (II)
- or a salt thereof, a solvate thereof, a tautomer thereof a stereoisomer thereof, or a mixture thereof;
- and
- an aldehyde of formula (III)
- or a salt thereof, a solvate thereof, a stereoisomer thereof, or a mixture thereof,
- wherein:
- R1, R2, R3, R4, R5, and R6 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, an optionally substituted arylalkyl, an optionally substituted aryl, an optionally substituted alkoxy, and an optionally substituted alkylthio;
- R7 is selected from the group consisting of a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, and an optionally substituted arylalkyl;
- R8 is selected from the group consisting of a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, an optionally substituted arylalkyl, and an optionally substituted aryl;
- and
- R9 is selected from the group consisting of a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, an optionally substituted arylalkyl, and an optionally substituted aryl.
10 more elements
Dependencies are inferred from the claim text.