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US 11,231,650 B2Granted
Chemically amplified negative resist composition and resist pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsMasaaki Kotake, Satoshi Watanabe, Keiichi Masunaga
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Abstract
A negative resist composition comprising an onium salt of arenesulfonic acid having a bridged ring-containing group and a base polymer is provided, the onium salt being capable of generating a bulky acid having an appropriate strength and controlled diffusion. When the resist composition is processed by lithography, a dot pattern of rectangular profile having high resolution and reduced LER is formed.
Claims17
A chemically amplified negative resist composition comprising
- (A) an acid generator containing an onium salt having the formula (A):
- wherein X1 and X2 are each independently methylene, propane-2,2-diyl or ether bond,
- L is a single bond, ester bond, sulfonic acid ester bond, carbonate bond or carbamate bond,
- R1 and R2 are each independently a C1-C20 monovalent hydrocarbon group which may contain a heteroatom,
- m1 and m2 are each independently an integer of 0 to 2, m3 is 0 or 1, n1 is an integer satisfying 1≤n1≤5+2m1, n2 is an integer satisfying 0≤n2≤4+2 m2, n3 is an integer satisfying 0≤n3≤8+4 m3,
- A+ is a sulfonium cation having the formula (A-A), an iodonium cation having the formula (A-B), or an ammonium cation having the formula (A-C):
- wherein R3A, R3B, R3C, R4A, R4B, R5A, R5B, and R5C are each independently a C1-C20 monovalent hydrocarbon group which may contain a heteroatom, R5D is hydrogen or a C1-C20 monovalent hydrocarbon group which may contain a heteroatom, any two of R3A, R3B and R3C or any two of R5A, R5B, R5C and R5D may bond together to form a ring with the sulfur or nitrogen atom to which they are attached, and
- (B) a base polymer containing a polymer comprising recurring units having the formula (B1):
- wherein RA is hydrogen, fluorine, methyl or trifluoromethyl,
- R11 is each independently halogen, an optionally halogenated C2-C8 acyloxy group, optionally halogenated C1-C6 alkyl group, or optionally halogenated C1-C6 alkoxy group,
- A1 is a single bond or C1-C10 alkanediyl group in which an ether bond may intervene in a carbon-carbon bond,
- t1 is 0 or 1, x1 is an integer of 0 to 2, a is an integer satisfying 0≤a≤5+2x1−b, and b is an integer of 1 to 3.
9 more elements
Dependencies are inferred from the claim text.