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US 11,230,788 B2Granted
Electrodeposition liquid and electrodeposition-coated article
AssigneeMitsubishi Materials Corporation
InventorsKoji Hirano, Shintaro Iida, Jyunko Hirata, Hideaki Sakurai
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Abstract
Provided is an electrodeposition dispersion including a polyamide-imide resin, a polar solvent, water, a poor solvent, and a base, in which the polar solvent is an organic solvent having a boiling point of higher than 100° C. and D(S-P) represented by a formula (1) satisfying a relationship of D(S-P)<6, and a weight-average molecular weight of the polyamide-imide is 10×104 to 30×104 or a number-average molecular weight of the polyamide-imide is 2×104 to 5×104. D(S-P)=[(dDS−dDP)2+(dPS−dPP)2+(dHS−dHP)2]1/2 (1)
Claims6
An electrodeposition dispersion comprising:
- a polyamide-imide resin;
- a polar solvent;
- water;
- a poor solvent having a solubility of polyamide-imides of 1 g/100 g-the solvent or less;
- and
- a base,
- wherein the polar solvent is an organic solvent having a boiling point of higher than 100° C. and D(S-P) represented by a formula (1) satisfying a relationship of D(S-P)<6, where D(S-P) represents a Hansen solubility parameter value (HSP value),
- a weight-average molecular weight of the polyamide-imide resin is 10×104 to 30×104 or a number-average molecular weight of the polyamide-imide resin is 2×104 to 5×104,
- an average size of the polyamide-imide resin particles is 400 nm or less,
- D(S-P)=[(dDS−dDP)2+(dPS−dPP)2+(dHS−dHP)2]1/2 (1)
- where dDS represents a dispersion term of an HSP value of the polar solvent, dDP represents a dispersion term of an HSP value of the polyamide-imide resin, dPS represents a polarity term of the HSP value of the polar solvent, dPP represents a polarity term of the HSP value of the polyamide-imide resin, dHS represents a hydrogen bonding term of the HSP value of the polar solvent, and dHP represents a hydrogen bonding term of the HSP value of the polyamide-imide resin,
- the poor solvent is selected from the group consisting of isopropyl alcohol, 1-methoxy-2-propanol and cyclohexanone, and
- the average size of the polyamide-imide resin particles is in a range of 130 to 290 nm.
10 more elements
Dependencies are inferred from the claim text.