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US 11,230,618 B2Granted
Modified conjugated diene-based polymer and method of preparing the same
AssigneeLG Chem, Ltd.
InventorsJi Eun Kim, Won Taeck Lim, Won Mun Choi, Dae June Joe
Life of this patent
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Abstract
The present invention relates to a modifier represented by Formula 1, a method of preparing the same, a modified conjugated diene-based polymer having a high modification ratio which includes a modifier-derived functional group, and a method of preparing the polymer.
Claims9
A modified conjugated diene-based polymer comprising a functional group derived from a modifier represented by Formula 1:
- wherein, in Formula 1,
- R1, R4, and R5 are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent selected from the group consisting of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms,
- R2 is a divalent hydrocarbon group having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent selected from the group consisting of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, and
- R3 is a connecting group represented by Formula 2 or Formula 3,
- wherein, in Formula 2 or Formula 3,
- R6 is a monovalent hydrocarbon group having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent selected from the group consisting of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms;
- or a substituent represented by Formula 2-1,
- R7 is a divalent hydrocarbon group having 1 to 20 carbon atoms which unsubstituted or substituted with at least one substituent selected from the group consisting of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, and
- R8 to R10 are each independently a divalent hydrocarbon group having 1 to 20 carbon atoms which is unsubstituted or substituted with an alkyl group having 1 to 20 carbon atoms,
- wherein, in Formula 2-1,
- R11 is a divalent hydrocarbon group having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent selected from the group consisting of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, and
- R12 and R13 are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent selected from the group consisting of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms.
9 more elements
Dependencies are inferred from the claim text.