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US 11,220,588 B2Granted
Fluoroelastomer composition
AssigneeSolvay Specialty Polymers Italy S.P.A.
InventorsMatteo Fantoni, Marco Avataneo, Stefano Bossolo
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Abstract
The invention pertains to a (per)fluoroelastomer composition comprising at least one (per)fluoroelastomer comprising iodine and/or bromine atoms, at least one polyunsaturated compound, at least one organic peroxide and at least one organic compound selected from the group consisting of (thio)urea compounds, cyclic addition products of ammonia or primary amine and aldehyde; (thio)carbamates.
Claims24
A (per)fluoroelastomer composition comprising:
- at least one (per)fluoroelastomer [fluoroelastomer (A)], said fluoroelastomer (A) comprising iodine and/or bromine atoms and having a backbone comprising:
- recurring units derived from tetrafluoroethylene (TFE);
- recurring units derived from at least one perfluorinated monomer selected from the group consisting of:
- PAVE monomers, wherein the PAVE monomers are perfluoroalkylvinylethers complying with formula CF2═CFORf1 in which Rf1 is a C1-C6 perfluoroalkyl;
- and
- MOVE monomers, wherein the MOVE monomers are perfluoro-oxyalkylvinylethers complying with formula CF2═CFOX0, in which X0 is (i) a C1-C12 perfluorooxyalkyl having one or more ether groups;
- or (ii) a group of formula -CF2ORf2 in which Rf2 is a C1-C6 perfluoroalkyl;
- optionally, recurring units derived from vinylidene fluoride (VDF) in an amount of up to 30% by moles, with respect to the total moles of recurring units;
- optionally, recurring units derived from at least one perfluorinated C3-C8 alpha- olefin, in an amount of up to 5% moles, with respect to the total moles of recurring units;
- optionally, recurring units derived from at least one fluorine-free alpha-olefin, in an amount of up to 10% moles, with respect to the total moles of recurring units;
- and
- optionally, recurring units derived from at least one bis-olefin [bis-olefin (OF)];
- from 0.5 to 5 weight parts, per 100 parts by weight of said fluoroelastomer (A), of at least one polyunsaturated compound selected from the group consisting of bis-olefins of formulae (OF-1), (OF-2) and (OF-3):
- wherein j is an integer between 2 and 10, and R1, R2, R3, R4, equal or different from each other, are H, F or C1-5 alkyl or (per)fluoroalkyl-group;
- wherein each of A, equal or different from each other and at each occurrence, is independently selected from F, Cl, and H;
- each of B, equal or different from each other and at each occurrence, is independently selected from F, Cl, H and ORB, wherein RB is a branched or straight chain alkyl radical which can be partially, substantially or completely fluorinated or chlorinated;
- E is a divalent group having 2 to 10 carbon atoms, optionally fluorinated, which may be inserted with ether linkages;
- wherein E, A and B have the same meaning as above defined;
- R5, R6, R7, equal or different from each other, are H, F or C1-5 alkyl or (per)fluoroalkyl group
- from 0.1 to 3 weight parts, per 100 parts by weight of said fluoroelastomer (A), of at least one organic peroxide;
- from 0.1 to 10 weight parts, per 100 parts by weight of said fluoroelastomer (A), of at least one organic compound [compound (C)] selected from the group consisting of:
- urea compounds of formula (U):
- wherein E is O, and each of Ru, equal to or different from each other, is independently selected from the group consisting of hydrogen and C1-C6 hydrocarbon groups;
- cyclic addition products of ammonia or primary amine and aldehyde;
- and
- carbamates of formula (C):
- wherein E is oxygen;
- Rb is a C1-C36 hydrocarbon group, and Re is H or a C1-C6 alkyl group.
25 more elements
Dependencies are inferred from the claim text.