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US 11,198,657 B2Granted
Method for producing conjugated diene
AssigneeKuraray Co., Ltd.
InventorsYutaka Suzuki, Masaki Shimizu
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Abstract
A method for producing a conjugated diene, including a step A of allowing an α-olefin and formaldehyde to react with each other to produce a γ,δ-unsaturated alcohol in the presence of an alcohol; and a step B of subjecting the γ,δ-unsaturated alcohol to a dehydration reaction at 135 to 210° C. in the presence of an aqueous solution of an acidic catalyst.
Claims9
A method for producing a conjugated diene, the method consisting of:
- reacting an α-olefin and formaldehyde with each other to produce a reaction liquid comprising a γ,δ-unsaturated alcohol;
- washing the reaction liquid to obtain a washed reaction liquid, wherein the washing comprises contacting the reaction liquid with an alkaline aqueous solution, and wherein the washed reaction liquid comprises an upper organic layer comprising the γ,δ-unsaturated alcohol;
- separating the upper organic layer from the washed reaction liquid to obtain a separated organic layer, then;
- distilling the separated organic layer to obtain a purified γ,δ-unsaturated alcohol;
- then
- subjecting the γ,δ-unsaturated alcohol to a dehydration reaction at 135 to 210° C. in the presence of an aqueous solution of an acidic catalyst, to obtain a conjugated diene, and
- optionally, purifying the conjugated diene.
4 more elements
Dependencies are inferred from the claim text.