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US 11,167,267 B2Granted
Removing and cleaning dehydrogenation catalysts
AssigneeNOVA Chemicals (International) S.A.
InventorsXiaoliang Gao, Vasily Simanzhenkov, Shahin Goodarznia, Marie Barnes, David Sullivan
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Abstract
Oxidative dehydrogenation catalysts including mixed oxides of Mo, V, Nb, Te, and optionally a promoter may be dissolved in aqueous solutions of oxalic acid. This permits the removal of catalyst and catalyst residues from reactors for the oxidative dehydrogenation of paraffins and particularly ethane.
Claims14
A method to remove from one or more vessels and associated piping a catalyst selected from the group consisting of:
- i) catalysts comprising
- Mo0.9-1.1V0.1-1Nb0.1-0.2Te0.01-0.17X0-2Od
- wherein:
- X is selected from Pd, Sb, Ba, Al, W, Ga, Bi, Sn, Cu, Ti, Fe, Co, Ni, Cr, Zr, Pt, and Ca,
- and d is a number to satisfy the valence of the catalyst;
- and
- ii) catalysts of the formula
- MoaVbNbcTeeOd
- wherein:
- a is from 0.75 to 1.25;
- b is from 0.1 to 0.5;
- c is from 0 to 0.5;
- e is from 0 to 0.35;
- and
- d is a number to satisfy the valence state of the catalyst
- wherein the catalyst is supported on an alumina support;
- the method comprising contacting the catalyst with from 10 to 100 ml of a not less than 0.5 molar solution of oxalic acid per 1 to 5 g of catalyst at a temperature from 20° C. to 100° C. for a period of time of not less than 1 hour, wherein contacting the catalyst dissolves the catalyst in the solution of oxalic acid.
14 more elements
Dependencies are inferred from the claim text.