Cobalt catalyst comprising a support comprising a mixed oxide phase including cobalt and/or nickel produced from an organic compound from the family of carboyxyanhydrides
AssigneeIfp Energies Nouvelles
InventorsDamien Delcroix, Manuel Corral Valero
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Abstract
The present invention relates to a catalyst containing an active cobalt phase, deposited on a support comprising alumina, silica or silica-alumina, said support containing a mixed oxide phase containing cobalt and/or nickel, said catalyst has been prepared by introducing at least one organic compound of the family of carboxyanhydrides. The invention also relates to the process for the preparation thereof, and to the use thereof in the field of Fischer-Tropsch synthesis processes.
Claims13
A process for preparing a catalyst containing an active cobalt phase, deposited on a support comprising alumina, silica or silica-alumina, said support containing a mixed oxide phase containing cobalt and/or nickel, said process comprising:
- a) bringing a support comprising alumina, silica or silica-alumina into contact with at least one solution containing at least one precursor of cobalt and/or of nickel, then drying at a temperature below 200° C. and calcining at a temperature of between 700° C. and 1200° C., so as to obtain a mixed oxide phase containing cobalt and/or nickel in the support, then
- b) bringing said support containing said mixed oxide phase into contact with at least one solution containing at least one precursor of cobalt,
- c) bringing said support containing said mixed oxide phase into contact with at least one organic compound that is an O-carboxyanhydride that is 5-methyl-1,3-dioxolane-2,4-dione or 2,5-dioxo-1,3-dioxolane-4-propanoic acid, or an N-carboxyanhydride that is 2,5-oxazolidinedione or 3,4-dimethyl-2,5-oxazolidinedione, b) and c) being able to be performed separately, in any order, or at the same time, and
- d) optionally then drying at a temperature below 200° C.
Dependencies are inferred from the claim text.