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US 11,155,674 B2Granted
Polymerizable sulfonamide compounds and polymers thereof
AssigneeMassachusetts Institute of Technology
InventorsJeremiah A. Johnson, Mao Chen, Mingjun Huang, Wenxu Zhang
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Abstract
Methods, compositions, reagents, and systems that allow for the preparation and utilization of sulfonamide salt polymer electrolytes are disclosed herein. Methods and reagents to prepare sulfonamide salt monomers are also disclosed herein. The sulfonamide salt polymer electrolytes can be used as components in energy storage devices, conductive materials, electrochemical cells, gels, adhesives, and drug delivery vehicles.
Claims22
A compound of Formula (I):
- wherein:
- R1 is optionally substituted alkyl or optionally substituted phenyl;
- X+ is a counterion;
- X1, X2, X3, X4 and X5 are independently hydrogen;
- halogen;
- optionally substituted, cyclic or acyclic alkyl;
- optionally substituted, cyclic or acyclic alkenyl;
- optionally substituted, cyclic or acyclic heteroalkenyl;
- optionally substituted, cyclic or acyclic alkynyl;
- optionally substituted, cyclic or acyclic heteroalkynyl;
- —OR2;
- —N(R3)2;
- or —SR2;
- each R2 independently is hydrogen;
- optionally substituted, cyclic or acyclic alkyl;
- optionally substituted, cyclic or acyclic heteroalkyl;
- optionally substituted, cyclic or acyclic alkenyl;
- optionally substituted, cyclic or acyclic heteroalkenyl;
- optionally substituted, cyclic or acyclic alkynyl;
- optionally substituted, cyclic or acyclic heteroalkynyl;
- optionally substituted aryl;
- optionally substituted heteroaryl;
- an oxygen protecting group;
- or a sulfur protecting group;
- and
- each R3 is independently hydrogen;
- optionally substituted, cyclic or acyclic alkyl;
- optionally substituted, cyclic or acyclic heteroalkyl;
- optionally substituted, cyclic or acyclic alkenyl;
- optionally substituted, cyclic or acyclic heteroalkenyl;
- optionally substituted, cyclic or acyclic alkynyl;
- optionally substituted, cyclic or acyclic heteroalkynyl;
- optionally substituted aryl;
- or optionally substituted heteroaryl;
- a nitrogen protecting group;
- or two R3 are taken together to form an optionally substituted heterocyclic moiety;
- provided that at least one of X1, X2, X3, X4 and X5 comprises optionally substituted, cyclic or acyclic alkenyl;
- optionally substituted, cyclic or acyclic heteroalkenyl;
- optionally substituted, cyclic or acyclic alkynyl;
- or optionally substituted, cyclic or acyclic heteroalkynyl;
- and at least two of X1, X2, X3, X4 and X5 are fluorine.
38 more elements
Dependencies are inferred from the claim text.