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US 11,145,888 B2Granted
Lithium secondary battery
AssigneeSK Innovation Co., Ltd.
InventorsDock Young Yoon, Jee Hee Lee, Sang Jin Kim
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Abstract
A lithium secondary battery includes a cathode, an anode and a non-aqueous electrolyte. The anode includes an anode active material which contains a mixture of an artificial graphite and a natural graphite. A sphericity of the natural graphite is 0.96 or more. The lithium secondary battery including the anode has improved life-span and power properties.
Claims4
A lithium secondary battery, comprising:
- a cathode;
- an anode comprising an anode active material comprised of a mixture of an artificial graphite and a natural graphite, wherein a sphericity of the natural graphite is 0.98 or more;
- and
- a non-aqueous electrolyte,
- wherein an average particle diameter (D50) of the natural graphite is in a range from 9 μm to 14 μm, and a mixing weight ratio of the natural graphite and the artificial graphite is in a range from 9:1 to 1:1;
- and
- an anode expansion rate represented by Equation 1 below is 20% or less:
- anode expansion rate (%)=100×(T2-T1)/(T1) [Equation 1]
- wherein T1 is a thickness of the anode at 0% state of charge (SOC), and T2 is a thickness of the anode at 100% SOC;
- and
- wherein a pellet density change rate of the natural graphite which is represented by Equation 2 is 0.06 or less:
- Pellet density change rate=(Da-Db)/(a-b) [Equation 2]
- wherein Da represents a pellet density (g/cc) measured by inputting 2.5 g of the natural graphite in a hole with a 1 cm diameter and then applying a pressure of 8 kN for 5 seconds, Db represents a pellet density measured by applying a pressure of 1 kN for 5 seconds, a represents 8 kN and b represents 1 kN.
10 more elements
Dependencies are inferred from the claim text.