Thermally conductive polyorganosiloxane composition
AssigneeMomentive Performance Materials Japan LLC
InventorsDaigo Hirakawa, Masanori Takanashi, Atsushi Sakamoto
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Abstract
The present invention relates to a thermally conductive polysiloxane composition that provides a cured product having excellent tackiness and flexibility in which the composition contains (A) a thermally conductive filler, (B) a siloxane compound having an alkoxysilyl group and a linear siloxane structure, (C) a polyorganosiloxane having at least two alkenyl groups bonded to silicon atoms per molecule, (D1) a linear polyorganohydrogensiloxane represented by the general formula (4), (D2) a polyorganohydrogensiloxane having per molecule at least three units represented by the general formula (5), and (E) a platinum catalyst.
Claims3
A thermally conductive polysiloxane composition comprising:
- (A) a thermally conductive filler;
- (B) a siloxane compound having an alkoxysilyl group and a linear siloxane structure;
- (C) a polyorganosiloxane having at least two alkenyl groups bonded to silicon atoms per molecule;
- (D1) a linear polyorganohydrogensiloxane represented by the following general formula (4):
- wherein:
- R7 is a hydrogen atom,
- R8 is each independently a monovalent hydrocarbon group having no aliphatic unsaturated bond and having 1 to 12 carbon atoms, and
- f is 1 to 200;
- (D2) a polyorganohydrogensiloxane having per molecule at least three units represented by the following general formula (5):
- R9gR10hSiO({4−(g+h)}/2) (5)
- wherein:
- R9 is each independently a monovalent hydrocarbon group having no aliphatic unsaturated bond and having 1 to 12 carbon atoms,
- R10 is a hydrogen atom,
- g is an integer of 0 to 2,
- h is an integer of 1 or 2, and
- g+h is an integer of 1 to 3, with the proviso that a case in which g is 1 and h is 1 is excluded;
- and
- (E) a platinum catalyst,
- wherein (D2) is a polyorganohydrogensiloxane comprising a R112HSiO1/2 unit, wherein R11 is synonymous with R9, and a SiO4/2 unit, and having at least three hydrogen atoms bonded to silicon atoms per molecule,
- wherein a ratio ((HD1+HD2)/ViC) of a sum (HD1+HD2) of a number HD1 of hydrogen atoms bonded to silicon atoms of (D1) and a number HD2 of hydrogen atoms bonded to silicon atoms of (D2) to a number ViC of the alkenyl groups of (C) is 0.85 or less, and
- wherein a ratio of HD1:HD2 is in a range of from 9:1 to 8:2.
Dependencies are inferred from the claim text.