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US 11,142,519 B2Granted
Pesticidally active pyrazole derivatives
AssigneeSyngenta Participations AG
InventorsMyriem El Qacemi, Aurelien Bigot, Andrew Edmunds, Julien Daniel Henri Gagnepain, André Jeanguenat, Thomas Pitterna, André Stoller, Davide Sabbadin, Regis Jean Georges Mondiere, Denis Gribkov
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Abstract
Compounds of formula (I) as defined herein, to processes for preparing them, to pesticidal, in particular insecticidal, acaricidal, molluscicidal and nematicidal compositions comprising them and to methods of using them to combat and control pests such as insect, acarine, mollusc and nematode pests.
Claims14
A compound of formula (I),
- wherein
- R1 is selected from H, C1-C6-alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C3-C7 cycloalkyl, C3-C7 cycloalkyl-C1-C3-alkyl, C1-C6-alkylcarbonyl, C1-C6-alkoxycarbonyl, aryl(C0-C3)-alkyl and heteroaryl(C0-C3)-alkyl, wherein each of C1-C6-alkyl, C2-C6alkenyl, C2-C6 alkynyl, C3-C7 cycloalkyl, C3-C7 cycloalkyl-C1-C3-alkyl, C1-C6-alkylcarbonyl, C1-C6-alkoxycarbonyl, aryl(C0-C3)-alkyl and heteroaryl(C0-C3)-alkyl is unsubstituted or substituted with 1 to 7 substituents independently selected from halogen, cyano, C1-C6-alkoxy and C1-C6-alkoxycarbonyl;
- Q is selected from H, hydroxy, —C(═O)H, C1-C6-alkyl, C1-C6-alkoxy, C2-C6 alkenyl, C2-C6 alkynyl, C3-C7 cycloalkyl, C3-C7 heterocycloalkyl, C3-C7 cycloalkyl-C1-C3-alkyl, C1-C3-alkyl-C3-C7 cycloalkyl, aryl(C0-C3)-alkyl, heteroaryl(C0-C3)-alkyl, N—C1-C6-alkylamino, N—C1-C6-alkylcarbonylamino and N,N-di (C1-C6-alkyl)amino, wherein each of C1-C6-alkyl, C1-C6-alkoxy, C2-C6 alkenyl, C2-C6 alkynyl, C3-C7 cycloalkyl, C3-C7 heterocycloalkyl, C3-C7 cycloalkyl-C1-C3-alkyl, C1-C3-alkyl-C3-C7 cycloalkyl, aryl(C0-C3)-alkyl, heteroaryl(C0-C3)-alkyl, N—C1-C6-alkylamino, N—C1-C6-alkylcarbonylamino and N,N-di (C1-C6-alkyl)amino is unsubstituted or substituted with 1 to 7 substituents independently selected from halogen, hydroxyl, nitro, amino, cyano, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-alkoxycarbonyl, —C(═O)OH, C1-C6-alkylcarbamoyl, —C(═O)NH2, —C(═S)NH2, C3-C6-cycloalkylcarbamoyl and phenyl;
- W is O or S;
- L is selected from
- wherein
- indicates the bond to the group
- T is a 5-membered heteroaryl of formula
- wherein
- indicates the bond to the group
- D1 is selected from CR9a, N, NR9b, O and S;
- D2 is selected from CR10a, N, NR10b, O and S;
- D3 is C or N;
- D4 is selected from CR11a, N, NR11b, O and S;
- D5 is C or N;
- with the proviso that at least one of D1, D2 and D4 is selected from N, O and S, that no more than one of D1, D2 and D4 is O or S, and that no more than three of D1, D2, D3, D4 and D5 are N and that D5 is C when L is L1, L6, L10, L11, L38, L39 and L43;
- R6b, R7b, R8b, R9b, R10b and R11b are independently selected from H, halogen, cyano, nitro, amino, C1-C6-alkyl, C1-C6-alkoxy, C3-C7 cycloalkyl, C1-C6-alkylcarbonyl, C1-C6-alkylsulfanyl, C1-C6-alkylsulfinyl and C1-C6-alkylsulfonyl, wherein each of C1-C6-alkyl, C1-C6-alkoxy, C3-C7 cycloalkyl, C1-C6-alkylcarbonyl, C1-C6-alkylsulfanyl, C1-C6-alkylsulfinyl and C1-C6-alkylsulfonyl is unsubstituted or substituted with 1 to 7 halogen;
- R6b, R7b, R8b, R9b, R10b and R11b are independently selected from H and C1-C6-alkyl, wherein C1-C6-alkyl is unsubstituted or substituted with 1 to 7 halogen;
- Z1 is selected from C1-C6-alkyl, C3-C7 heterocycloalkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl and C3-C6-halocycloalkyl, wherein each of C1-C6-alkyl, C3-C7 heterocycloalkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl and C3-C6-halocycloalkyl is unsubstituted or substituted with 1 to 5 substituents independently selected from halogen, hydroxy, nitro, amino, cyano, C1-C6-alkoxy, C1-C6-alkoxycarbonyl, hydroxycarbonyl, C1-C6-alkylcarbamoyl, C3-C6-cycloalkylcarbamoyl and phenyl;
- U is selected from C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C5-cycloalkoxy, C3-C5-halocycloalkoxy, C3-C5-cycloalkyl, C3-C5-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C3-alkynyl, —S—C3-C5-cycloalkyl, —S—C3-C5-halocycloalkyl, —SO—C3-C5-cycloalkyl, —SO—C3-C5-halocycloalkyl, —SO2—C3-C5-cycloalkyl, —SO2—C3-C5-halocycloalkyl, —O—C2-C4-alkenyl, —O—C2-C4-haloalkenyl, —NHCN, —SO2F, —O—SO2—C1-C4-alkyl, —O—SO2—C1-C4-haloalkyl and OH;
- Z3 is selected from H, C1-C6-alkyl, C1-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkinyl, aryl and heteroaryl, wherein each of C1-C6-alkyl, C1-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkinyl, aryl and heteroaryl, is unsubstituted or substituted with 1 to 7 substituents independently selected from halogen, hydroxy, nitro, amino, cyano, C1-C6-alkoxy, C1-C6-alkoxycarbonyl, —C(═O)OH, C1-C6-alkylcarbamoyl, C3-C6-cycloalkylcarbamoyl and phenyl;
- with the proviso that when L is L46, U is not C1-C4-alkoxy or C1-C4-haloalkoxy;
- or an agrochemically acceptable salt or N-oxide thereof.
20 more elements
Dependencies are inferred from the claim text.