Translucent nanocrystalline glass ceramic
AssigneeAduro Material AB
InventorsHåkan Engqvist, Le Fu, Wei Xia
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Abstract
The present invention provides a material composition and a process of producing translucent ZrO2—SiO2 nanocrystalline glass ceramic (NCGC) with ultra-high flexural strength. The method comprises the following step: (1) prepare homogenous ZrO2-SiO2 nano-sized powder with high purity via a sol-gel method; (2) pressure assisted sintering of ZrO2-SiO2 nano-sized sol-gel powder to obtain translucent ZrO2-SiO2 NCGC. The invention also includes materials manufactured using the method.
Claims27
A method for manufacturing translucent ZrO2—SiO2 nanocrystalline glass ceramic, comprising the steps of:
- Providing a first solution by mixing a first precursor comprising silicon (IV), a solvent and an acidic aqueous solution, wherein the acidic aqueous solution has a concentration of 0.1-1 mol/L, whereby the first precursor is hydrolyzed;
- Providing a second solution by mixing a second precursor comprising zirconium (IV) and a solvent;
- Combining the first and second solutions, wherein the molar ratio between Zr and Si in said solution ranges from 20:80 to 90:10;
- Hydrolyzing the second precursor and polymerizing the combined solution by addition of an acidic aqueous solution having a concentration of 5-12 mol/L, to form a sol;
- Ageing the sol to form a clear sol;
- Polymerizing the clear sol by addition of an acidic aqueous solution;
- Ageing the clear sol to form a gel;
- Drying the gel to form a xerogel;
- Micronising of the xerogel to form a powder, and optionally including particle size selection;
- Calcining the powder, optionally with pre-compaction or compaction during the calcination process;
- and
- Sintering the calcined powder, optionally with pre-compaction or compaction during the calcination process.
A precursor powder material for forming translucent glass ceramic material, the precursor powder material comprising SiO2 and 5-10 wt % of nanocrystalline tetragonal ZrO2, wherein the molar ratio between ZrO2 and SiO2 ranges from 60:40 to 80:20.
A translucent glass ceramic material having a microstructure of single crystalline ZrO2 spherical nanocrystals embedded in an amorphous SiO2 matrix, wherein the molar ratio between ZrO2 and SiO2 ranges from 60:40 to 80:20 and the material comprises 5-10 wt % of the ZrO2 spherical nanocrystals.
A dental restorative material comprising a translucent glass ceramic material having a microstructure of single crystalline ZrO2 spherical nanocrystals embedded in an amorphous SiO2 matrix, wherein the molar ratio between ZrO2 and SiO2 ranges from 60:40 to 80:20 and the material comprises 5-10 wt % of the ZrO2 spherical nanocrystals.
Dependencies are inferred from the claim text.