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US 11,141,961 B2Granted
Shrink films comprising a cyclic-olefin copolymer core
AssigneeExxonMobil Chemical Patents Inc.
InventorsLan Y. Cheng, Achiel J. M. Van Loon, Yong Yang
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Abstract
A multi-layered polyethylene film suitable for shrink applications including at least a core layer and at least one other layer adjacent thereto, the core layer including within a range from 5 wt % to 50 wt % of a cyclic olefin copolymer based on the weight of the core layer, and within a range from 50 wt % to 95 wt % of a polyethylene based on the weight of the core layer, wherein the cyclic olefin copolymer has a glass transition temperature (Tg) of at least 70° C.
Claims32
A multi-layered polyethylene film having:
- a dart drop of at least 7 g/um,
- a 1% TD secant flexural modulus of at least 280 to 460 MPa,
- a 1% MD secant flexural modulus of at least 280 to 460 MPa, and
- a TD shrink within a range from 20% to 36%,
- an MD shrink within a range from 55 to 90%;
- said film comprising at least a core layer and at least one other layer adjacent thereto, the core layer comprising within a range from 5 wt % to 50 wt % of a cyclic olefin copolymer based on the weight of the core layer, and within a range from 50 wt % to 95 wt % of a polyethylene based on the weight of the core layer,
- wherein:
- 1) the cyclic olefin copolymer has a glass transition temperature (Tg) of at least 80° C.,
- 2) the core layer is sandwiched between two polyethylene skin layers,
- 3) each skin layer independently comprises at least 50 wt % linear low density polyethylene and from 0.5 wt % to 20 wt % low density polyethylene by weight of each skin layer, and
- 4) the polyethylene of the core layer is:
- i) a linear low density polyethylene comprising from 0.5 to 20 wt % C4 to C12 α-olefin derived units by weight of the copolymer, the remainder of the copolymer comprising ethylene-derived units, ii) a low density polyethylene, or iii) a combination thereof.
9 more elements
Dependencies are inferred from the claim text.