# US 11,114,713 B2 · Thermal management systems for battery cells and methods of their manufacture > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,114,713 B2 - Document ID: US11114713B2 - Status: Granted - Kind: B2 - Application number: 16/447,824 - Filed: 2019-06-20 - Published: 2019-12-26 - Granted: 2021-09-07 - Earliest claimed: 2018-06-21 - Assignees: California Institute of Technology - Applicants: California Institute of Technology - Inventors: Eric T. Sunada; Scott N. Roberts; Benjamin I. Furst; Ratnakumar V. Bugga - Web page: https://patentgrep.com/patent/US11114713B2 ## CPC - H01M 10/6554: Rods or plates - H01M 10/6569: Fluids undergoing a liquid-gas phase change or transition, e.g. evaporation or condensation (heat pipes H01M10/6552) - H01M 10/04: Construction or manufacture in general (H01M10/058, H01M10/12, H01M10/28, H01M10/38 take precedence) - H01M 10/613: Cooling or keeping cold - H01M 10/653: characterised by electrically insulating or thermally conductive materials - H01M 10/6552: Closed pipes transferring heat by thermal conductivity or phase transition, e.g. heat pipes - H01M 10/6557: arranged between the cells - H01M 10/6567: Liquids - H01M 10/658: by thermal insulation or shielding - Y02E 60/10: Energy storage using batteries - H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION ## Abstract Thermal management systems for battery cells and methods for their additive manufacture are provided. The thermal management systems include at least one heat pipe that physically contacts the battery cell and conforms to its geometry. Each battery cell is deposited within a separate heat pipe, and each heat pipe is disposed on a base plate, which itself connects to a heat sink. In many embodiments, the heat pipe is a two-phase heat exchanger having three major components: liquid channels, wick elements, and vapor channels. In such embodiments, the wick component comprises a porous body configured to be disposed between the liquid channels and vapor channels. The wick component may be made using a stochastic additive manufacturing process such that the wick component may take any configuration and/or such that the wick component may be directly integrated into the body of the heat pipe as a unitary piece thereof. In other embodiments, the heat pipe is a cavity with flow channels in which fluid can be pumped through. In some such embodiments, the fluid can occupy the heat pipe in a one-phase or two-phase state. This unitary heat pipe is part of a monolithic thermal management system. ## Claims ### Claim 1 A thermal management system for batteries comprising: at least one battery holding compartment comprising: a non-porous interior wall defining the battery holding compartment configured to contain at least one battery cell, the non-porous interior wall being configured to conformally contact at least a portion of the at least one battery cell and configured to transport heat to or from the battery cell through conduction; a cavity disposed adjacent to the non-porous interior wall in a direction distal from the at least one battery cell; a non-porous exterior wall disposed adjacent to the cavity; a working fluid disposed within the cavity; and a heat transfer plate disposed in thermal contact on a first side with at least the working fluid, and on a second side with a cooling or heating environment; wherein the cavity further comprises: a porous wick; and a vapor space disposed adjacent to the porous wick; wherein the porous wick is an enclosed system configured to contain and cycle the working fluid between a liquid and a vapor phase, such that when the working fluid is in a liquid phase it saturates and travels through the porous wick allowing for the transfer of heat to or from the interior wall and the heat transfer plate, and such that when the working fluid is in a vapor phase it escapes the porous wick into the vapor space to transfer heat to or from the heat transfer plate; wherein the thermal management system and the at least one battery holding compartment, including at least the non-porous interior and exterior walls, the porous wick, and the heat transfer plate are all formed as a single continuous monolithic structure. ### Claim 2 (depends on 1) The thermal management system of claim 1, wherein the material of each the non-porous interior wall and exterior wall is separately selected from the group consisting of alloys, ceramics, and plastics. ### Claim 3 (depends on 1) The thermal management system of claim 1, wherein the thickness of each of the non-porous interior wall and non-porous exterior wall ranges separately from 0.1 mm to 20 mm. ### Claim 4 (depends on 1) The thermal management system of claim 1, wherein the surface roughness of the non-porous interior and non-porous exterior wall separately forms capillary channels of less than 500 μm. ### Claim 5 (depends on 1) The thermal management system of claim 1, wherein the working fluid is selected from the group consisting of water, acetone, ammonia, ethanol, methanol, heptane, toluene, perfluorocarbon fluids, and hydrofluorocarbon fluids such as R-134a. ### Claim 6 (depends on 1) The thermal management system of claim 1, wherein the porous wick is formed of a material selected from the group consisting of alloys, ceramics, and plastics. ### Claim 7 (depends on 1) The thermal management system of claim 1, wherein the surface roughness of the porous wick forms capillary channels of less than 500 μm. ### Claim 8 (depends on 1) The thermal management system of claim 1, wherein the porous wick has a variable porosity ranging from pore sizes on the order of 0.1 μm to pore sizes on the order of 100 μm. ### Claim 9 (depends on 1) The thermal management system of claim 1, wherein the porous wick comprises at least one of: an interior porous wick disposed adjacent to and in physical contact with the interior wall; an exterior porous wick disposed adjacent to the vapor space; and at least one bridge porous wick connecting the interior porous wick and exterior porous wick. ### Claim 10 (depends on 9) The thermal management system of claim 9, wherein the thickness of the interior porous wick and exterior porous wick ranges separately up to 2 cm. ### Claim 11 (depends on 9) The thermal management system of claim 9, wherein each of the at least one bridge porous wicks has a separate thickness ranging from 0.1 mm to 2 cm. ### Claim 12 (depends on 9) The thermal management system of claim 9, further comprising a plurality of bridge porous wicks, wherein the plurality of bridge porous wicks are arranged in a regular array between the interior porous wick and exterior porous wicks. ### Claim 13 (depends on 9) The thermal management system of claim 9, further comprising a plurality of bridge porous wicks, wherein the plurality of bridge porous wicks are distributed heterogeneously about a perimeter of the interior porous wick. ### Claim 14 (depends on 9) The thermal management system of claim 9, further comprising at least one flow channel have a channel diameter greater than 100 micron, the at least one flow channel being incorporated into the porous wick such that working fluid may be transported therethrough. ### Claim 15 (depends on 1) The cavity of claim 1, further comprising: at least one flow channel; wherein the at least one flow channel is an enclosed system configured to contain and cycle the working fluid, allowing for the transfer of heat to or from the interior wall and the heat transfer plate; and wherein the thermal management system, including the at least one flow channel, is formed as a single continuous monolithic structure. ### Claim 16 (depends on 1) The thermal management system of claim 1, further comprising a plurality of battery holding compartments, wherein the plurality of battery holding compartments are formed as a single continuous monolithic structure. ### Claim 17 (depends on 16) The thermal management system of claim 16, wherein each of the adjacent battery holding compartments are fluidly interconnected such that working fluid may flow therebetween. ### Claim 18 (depends on 16) The thermal management system of claim 16, wherein each of the battery holding compartments in the plurality of battery holding compartments are separated by a thermal isolating structure disposed between at least a portion of the exterior walls of each two adjacent battery holding compartments. ### Claim 19 (depends on 18) The thermal management system of claim 18, wherein the thermal isolating structure defines a volume filled with a thermally isolating material selected from the group consisting of a phase change material, air, fiberglass, fiber, wool, or a vacuum. ### Claim 20 An additive manufacturing process for creating a single continuous monolithic thermal management system, the process comprising: the layer-by-layer deposition of at least one battery holding compartment comprising: a non-porous interior wall defining the battery holding compartment configured to contain at least one battery cell, the non-porous interior wall being configured to conformally contact at least a portion of the at least one battery cell and configured to transport heat to or from the battery cell through conduction; a cavity disposed adjacent to the non-porous interior wall in a direction distal from the at least one battery cell; a non-porous exterior wall disposed adjacent to cavity; a working fluid disposed within the cavity; a heat transfer plate disposed in thermal contact on a first side with at least the working fluid, and on a second side with a cooling or heating environment; wherein the cavity further comprises: a porous wick; and a vapor space disposed adjacent to the porous wick; wherein the porous wick is an enclosed system configured to contain and cycle the working fluid between a liquid and a vapor phase, such that when the working fluid is in a liquid phase it saturates and travels through the porous wick allowing for the transfer of heat to or from the interior wall and the heat transfer plate, and such that when the working fluid is in a vapor phase it escapes the porous wick into the vapor space to transfer heat to or from the heat transfer plate; wherein the thermal management system and the at least one battery holding compartment, including at least the non-porous interior and exterior walls, the porous wick, and the heat transfer plate are all formed as a single continuous monolithic structure.