Cathode active materials having improved particle morphologies
AssigneeApple Inc.
InventorsHongli Dai, Huiming Wu, Dapeng Wang
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Abstract
Mixed-metal oxides and lithiated mixed-metal oxides are disclosed that involve compounds according to, respectively, NixMnyCozMeαOβ and Li1+γNixMnyCozMeαOβ. In these compounds, Me is selected from B, Na, Mg, Al, Si, K, Ca, Sc, Ti, V, Cr, Fe, Cu, Zn, Ga, Ge, Zr, Nb, Mo, Ru, Ag, In, and combinations thereof; 0≤x≤1; 0≤y≤1; 0≤z<1; x+y+z>0; 0≤α≤0.5; and x+y+α>0. For the mixed-metal oxides, 1≤β≤5. For the lithiated mixed-metal oxides, −0.1≤γ≤1.0 and 1.9≤β≤3. The mixed-metal oxides and the lithiated mixed-metal oxides include particles having an average density greater than or equal to 90% of an ideal crystalline density.
Claims19
Particles comprising a compound Formula (IVa) represented by
- Co1-lM5lAlmOn (IVa)
- wherein
- M5 is B, Na, Mn, Ni, Mg, Ti, Ca, V, Cr, Fe, Cu, Zn, Al, Sc, Y, Ga, Zr, Mo, Ru, and any combination thereof,
- 0<1<0.50;
- 0<m≤0.05;
- and
- 0.9≤n≤2.6,
- wherein the particles have an average density greater than or equal to 90% of an ideal crystalline density of the particles.
Dependencies are inferred from the claim text.