# US 11,114,592 B2 · Light emitting diode > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,114,592 B2 - Document ID: US11114592B2 - Status: Granted - Kind: B2 - Application number: 17/194,223 - Filed: 2021-03-06 - Published: 2021-06-24 - Granted: 2021-09-07 - Earliest claimed: 2004-05-07 - Applicants: Bruce H. Baretz - Inventors: Bruce H. Baretz - Web page: https://patentgrep.com/patent/US11114592B2 ## CPC - H10H 20/8513: {having two or more wavelength conversion materials} - H10H 20/854: characterised by their material, e.g. epoxy or silicone resins - H10H 20/8506: {Containers} - H10H 20/852: Encapsulations - H10H 20/858: Means for heat extraction or cooling - F21K 9/232: specially adapted for generating an essentially omnidirectional light distribution, e.g. with a glass bulb - H10H 20/8515: {not being in contact with the bodies} - H10H: INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS - F21K: NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR ## Abstract A light emitting assembly comprising a solid state device, when and if coupleable with a power supply constructed and arranged to power the solid state device to emit from the solid state device a first wavelength radiation, and an enveloping vessel enhancing the luminescence of the solid-state device and providing a mechanism for arranging luminophoric medium in receiving relationship to said first, radiation, and which in exposure to said first radiation, is excited to responsively emit second wavelength radiation or to otherwise transfer its energy without radiation to a third radiative component. In a specific embodiment, monochromatic blue or UV light output from a light-emitting diode is converted to achromatic light without hue by packaging the diode with fluorescent organic and/or inorganic fluorescers and phosphors on the walls of the solid-state light envelope which keeps the diode and the fluorescers and phosphors under a vacuum or a rare or Noble gas. ## Claims ### Claim 1 A microelectronic device, comprising: at least one of a light emitting diode with a p-n junction operable to emit radiation when coupled with a power source; a plurality of optically transmissive enclosures; and at least one outer optically-transmissive enclosure the boundaries of which contain an inner space within which is a plurality of innermost, second optically-transmissive enclosure, the wall of which form the boundaries of an interior space in each second enclosure; wherein said interior space has within each at least one said light-emitting diode; and wherein a heat exchanger is disposed adjacent to the wall of the second optically-transmissive enclosure. ### Claim 2 (depends on 1) The device of claim 1, wherein a region of the inner space contains an atmospheric volume that is in thermal contact with the exterior walls of the at least one of the said second enclosures. ### Claim 3 (depends on 2) The device of claim 2, wherein the atmospheric volume is a vacuum with a vacuum pressure less than 501 millibar and more than 0.005 millibars. ### Claim 4 (depends on 2) The device of claim 2, wherein the atmospheric volume contains a gas other than air with a pressure less than 2,001 millibar and more than 500 millibar, wherein the gas has a protecting or enhancing effect. ### Claim 5 (depends on 4) The device of claim 4, further comprising a luminescent element covalently attached to the outer wall of a secondary enclosure; wherein said semiconductor light-emitting diodes emit a primary radiation; wherein said luminescent element is radiatively excited by the primary radiation so as to cause the luminescent element to emit secondary radiation, wherein the luminescent element is exposed to a gas. ### Claim 6 (depends on 4) The device of claim 4, further comprising a luminophor coated onto the exterior walls of a second enclosure; said walls including a glass; and said luminophor immersed within the inner space's atmospheric volume; wherein said luminophor's emission spectrum is variable based on the temperature of the atmospheric volume it experiences; and wherein the gaseous environment reversibly changes during the operation of the device such that the device acts as a sensor. ### Claim 7 (depends on 4) The device of claim 4, wherein heat is removed by conduction, convection, or by thermal radiation via the gas or vacuum, through the wall of the second optically-transmissive enclosure via the heat exchanger to the outside environment. ### Claim 8 (depends on 1) The device of claim 1, wherein the heat exchanger is a heat sink disposed within the inner space. ### Claim 9 (depends on 1) The device of claim 1, wherein the heat exchanger is a heat sink disposed within the interior space. ### Claim 10 A solid-state light emitting device, comprising: at least one single-die semiconductor light-emitting diode with a p-n junction including an optically-transmissive enclosure the boundaries of which form an inner space where in the inner space has a region of a gaseous environment other than air; and a secondary optically-transmissive enclosure within the inner space of the outer enclosure the boundaries of which form an interior space wherein the interior space has a region of a gaseous environment other than air, different than the gaseous environment in the inner space; wherein a heat exchanger is disposed adjacent to the boundaries of the secondary optically-transmissive enclosure. ### Claim 11 (depends on 10) The device of claim 10, wherein the at least one light-emitting diode to emit light when energized with an electrical current is in the inner space of said optically-transmissive enclosure. ### Claim 12 (depends on 11) The device of claim 11, further comprising a fluorescent, a phosphorescent, a thermo-luminescence or an electroluminescent material coated on the exterior walls of the second enclosure. ### Claim 13 (depends on 12) The device of claim 12, wherein the gas in the inner space is ammonia, nitrogen, argon, krypton or xenon or any combination thereof. ### Claim 14 (depends on 12) The device of claim 12, wherein the gas in the interior space contains argon, krypton or xenon or any combination thereof. ### Claim 15 (depends on 10) The device of claim 10, wherein the heat exchanger is a heat sink disposed within the inner space. ### Claim 16 (depends on 10) The device of claim 10, wherein the heat exchanger is a heat sink disposed within the interior space. ### Claim 17 A light-emission device, comprising: at least one of a single-die, a two-lead GaN semiconductor light-emitting diode die capable of emitting radiation said diode the donor; and a recipient luminophoric element for converting non-radiatively energy transferred from the donor to the luminophoric element; wherein the ground-state of the acceptor is capable of reducing the excited state lifetime of the donor; wherein the two-lead diode die is within the interior space of a secondary optically-transmissive enclosure with a layer of luminescent element, said element an acceptor; wherein the same or different luminescent element is in the interior space of each of a plurality of different secondary optically-transmissive enclosures, said element a converter; wherein the interior space of both the secondary optically-transmissive enclosure containing a light emitting diode die and the secondary optically-transmissive enclosures containing luminescent element includes a region of the same or different Noble or otherwise inert gas; wherein all of the secondary enclosures are within the inner space of an outer optically-transmissive enclosure; and wherein a heat exchanger is disposed in the inner space or the interior space. ### Claim 18 (depends on 17) The device of claim 17, wherein the luminescent material that is an acceptor includes cerium doped yttrium aluminum garnet. ### Claim 19 (depends on 17) The device of claim 17, wherein the converter includes an optically active, chiral luminescent material. ### Claim 20 (depends on 17) The device of claim 17, wherein heat is removed by conduction, convection, or by thermal radiation through a wall of the secondary optically-transmissive enclosure via the heat exchanger to the outside environment.