# US 11,114,216 B2 · Aluminum-resin composite, insulated aluminum wire, flat cable and processes for producing the same

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- Number: US 11,114,216 B2
- Document ID: US11114216B2
- Status: Granted
- Kind: B2
- Application number: 15/084,907
- Filed: 2016-03-30
- Published: 2016-07-21
- Granted: 2021-09-07
- Earliest claimed: 2013-10-03
- Assignees: Furukawa Electric Co., Ltd.
- Applicants: Furukawa Electric Co., Ltd.
- Inventors: Yong Hoon Kim; Shoji Koizumi
- Web page: https://patentgrep.com/patent/US11114216B2

## CPC

- H01B 7/02: Disposition of insulation
- B32B 15/08: of synthetic resin
- C22C 21/00: Alloys based on aluminium
- C22F 1/04: of aluminium or alloys based thereon
- H01B 3/306: {Polyimides or polyesterimides}
- H01B 3/308: {Wires with resins}
- H01B 7/0009: {Details relating to the conductive cores}
- H01B 7/08: Flat or ribbon cables
- H01B: CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES (selection for magnetic properties H01F1/00; waveguides H01P {; printed circuits H05K})
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- C22C: ALLOYS (treatment of alloys C21D, C22F)
- C22F: CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS (surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by this subclass, C23F17/00)

## Abstract

The present invention relates to an aluminum-resin composite and provides the aluminum-resin composite which is excellent in adhesive property between metal and resin and is applicable to a continuous production process such as a wire production process. Specifically, the present invention uses the aluminum-resin composite including a metal made of aluminum or an aluminum alloy and resin adhering to the metal via an alumina nanoporous layer formed on a surface of the metal. The alumina nanoporous layer contains alumina nanoparticles of 5 nm to 10 nm in average particle diameter and holes three-dimensionally communicating with one another.

## Claims

### Claim 1

An aluminum-resin composite comprising:
a metal made of aluminum or an aluminum alloy, and
a thermosetting resin adhering directly to an alumina nanoporous layer which is formed directly on a surface of the metal and contains alumina nanoparticles of 10 nm to 50 nm in average particle diameter, wherein the alumina nanoporous layer is formed by ablating the surface of the metal with laser radiation to form the nanoparticles adhered to the surface of the metal with nanospaces formed between the nanoparticles, wherein the thermosetting resin fills the nanospaces, and wherein a ten-point average roughness Rz of the surface of the metal is 2.1 μm to 10 μm in an interface between the metal and the thermosetting resin.

### Claim 2 (depends on 1)

The aluminum-resin composite according to claim 1, wherein the thermosetting resin contains at least one selected from the group consisting of polyimide, polyamideimide, polyesterimide, polyetherimide, polyimide hydantoin-modified polyester, formal, polyurethane, polyester, polyvinylformal, epoxy resin, phenol resin, and polyhydantoin.

### Claim 3 (depends on 1)

A process for producing the aluminum-resin composite as defined in claim 1, the process comprising the steps of:
forming the alumina nanoporous layer by ablating the surface of the metal with laser radiation to form the nanoparticles adhered to the surface of the metal with nanospaces formed between the nanoparticles, and
forming the thermosetting resin directly on the alumina nanoporous layer, wherein the resin fills the nanospaces.

### Claim 4 (depends on 1)

An insulated aluminum wire comprising the aluminum-resin composite according to claim 1, wherein:
said metal made of aluminum or an aluminum alloy forms a metal wire, and
said thermosetting resin adheres directly to said alumina nanoporous layer formed on said surface of the metal to form an insulation coating for coating the metal wire.

### Claim 5 (depends on 1)

A flat cable comprising the aluminum-resin composite according to claim 1, wherein:
said metal made of aluminum or an aluminum alloy forms metal conductors, and
said thermosetting resin adheres directly to said alumina nanoporous layer formed on the surface of each of the metal conductors to form a thermosetting resin layer for sandwiching each of the metal conductors from both sides of each of the metal conductors.

### Claim 6

An insulated aluminum wire comprising:
a metal wire made of aluminum or an aluminum alloy, and
a thermosetting resin for coating the metal wire adhered directly to an alumina nanoporous layer which is formed directly on a surface of the metal wire and contains alumina nanoparticles of 10 nm to 50 nm in average particle diameter, wherein the alumina nanoporous layer is formed by ablating the surface of the metal with laser radiation to form nanoparticles adhered to the surface of the metal wire with nanospaces formed between the nanoparticles, wherein the thermosetting resin fills the nanospaces, and wherein a ten-point average roughness Rz of the surface of the metal is 2.1 μm to 10 μm in an interface between the metal and the thermosetting resin.

### Claim 7 (depends on 6)

A process for producing the insulated aluminum wire as defined in claim 6, the process comprising the steps of:
forming the alumina nanoporous layer by ablating the surface of the metal wire with laser radiation to form nanoparticles adhered to the surface of the metal wire with nanospaces formed between the nanoparticles, and
forming the thermosetting resin directly on the alumina nanoporous layer, wherein the thermosetting resin fills the nanospaces.

### Claim 8

A flat cable comprising:
conductors made of aluminum or an aluminum alloy, and
a thermosetting resin layer adhered directly to each of the conductors from both sides of each of the conductors via an alumina nanoporous layer formed directly on a surface of each of the conductors, wherein the alumina nanoporous layer is formed by ablating the surface of each of the conductors with laser radiation to form nanoparticles of 10 nm to 50 nm in average particle diameter adhered to the surfaces of the conductors with nanospaces formed between the nanoparticles, wherein the thermosetting resin fills the nanospaces, and wherein a ten-point average roughness Rz of the surface of the metal is 2.1 μm to 10 μm in an interface between the metal and the thermosetting resin.

### Claim 9 (depends on 8)

A process for producing a flat cable as defined in claim 8, the process comprising the steps of:
forming the alumina nanoporous layer by ablating the surface of each of the conductors with laser radiation to form nanoparticles adhered to the surfaces of the conductors with nanospaces formed between the nanoparticles, and
forming the thermosetting resin layer directly on the alumina nanoporous layer on each of the conductors, wherein the thermosetting resin fills the nanospaces.