# US 11,111,853 B2 · Method for exhaust waste energy recovery at the internal combustion engine polygeneration plant

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 11,111,853 B2
- Document ID: US11111853B2
- Status: Granted
- Kind: B2
- Application number: 16/727,239
- Filed: 2019-12-26
- Published: 2020-07-02
- Granted: 2021-09-07
- Earliest claimed: 2018-12-26
- Applicants: Stanislav Sinatov
- Inventors: Stanislav Sinatov
- Web page: https://patentgrep.com/patent/US11111853B2

## CPC

- F01K 23/065: {the combustion taking place in an internal combustion piston engine, e.g. a diesel engine}
- F02C 3/34: with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
- F01K 23/10: with exhaust fluid of one cycle heating the fluid in another cycle (F01K17/025 takes precedence)
- B01D 2257/504: Carbon dioxide
- F02C 3/28: using a separate gas producer for gasifying the fuel before combustion
- F02C 3/30: Adding water, steam or other fluids {for influencing combustion, e.g. to obtain cleaner exhaust gases (F02C7/141, F02C7/30, F01D21/00, F01K21/04, F23D11/10 take precedence)}
- F02C 6/18: using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants (using waste heat as source of energy for refrigeration plants F25B27/02; using the waste heat of a gasturbine for steam generation or in a steam cycle see F01K23/10)
- F02G 2280/20: Rotary generators
- F05D 2260/61: Removal of CO2
- F05D 2270/08: to produce clean exhaust gases
- F25J 2210/42: Nitrogen
- F25J 2240/70: Steam turbine, e.g. used in a Rankine cycle
- F25J 2240/82: with waste heat recovery, e.g. in a combined cycle, i.e. for generating steam used in a Rankine cycle
- F25J 2270/14: External refrigeration with work-producing gas expansion loop
- Y02E 20/32: Direct CO2 mitigation
- F01K: STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES (gas-turbine or jet-propulsion plants F02; nuclear power plants, engine arrangements therein G21D)
- F02C: GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS (construction of turbines F01D; jet-propulsion plants F02K; construction of compressors or fans F04; generating combustion products of high pressure or high velocity F23R; using gas turbines in compression refrigeration plants F25B11/00)
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- F02G: HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS (steam engine plants, special vapour plants, plants operating on either hot gas or combustion-product gases together with other fluid F01K; gas-turbine plants F02C; jet-propulsion plants F02K); USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
- F05D: INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F25J: LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS {OR LIQUEFIED GASEOUS} MIXTURES BY PRESSURE AND COLD TREATMENT {OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE (cryogenic pumps F04B37/08; gas storage vessels, gas holders F17; filing vessels with, or discharging from vessels, compressed, liquefied or solidified gases F17C; refrigeration machines, plants, or systems F25B)}
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A method for exhaust waste energy recovery at the internal combustion engine polygeneration plant with the gas engine or gas turbine prime movers which includes supplying this plant with any on-site available methaneous gas (MG), converting from 20 to 30% of supplied MG into electric or mechanical power and producing a liquefied MG (LMG) co-product from the other 80-70% of supplied MG at a rate of 0.5-0.9 ton/h for each MW of engine output through converting and harnessing an engine exhaust as an effective refrigerant.

## Claims

### Claim 1

A method for an exhaust waste energy recovery at an internal combustion engine (ICE) polygeneration plant, comprising in combination:
supplying said polygeneration plant with a methaneous gas (MG) at a rate exceeding an amount of a fuel required for the ICE operation;
processing all the supplied MG to meet the parameters and quality standards specific by its following liquefaction;
selecting a type of the ICE for installation at the polygeneration plant from a group comprising a twin-shaft gas turbine and a lean burn supercharged reciprocating gas engine;
supplying the polygeneration plant with an atmospheric air which is at least partially used as a combustion air in a selected ICE;
pressurizing the combustion air with use of at least one compression means so providing a high pressure (HP) combustion air required for operation of the selected ICE;
burning a mixture of said fuel with the HP combustion air and following expanding a formed combustion gas down to a low-pressure (LP) in said selected ICE, resulting in producing a first part of a gross power output of said polygeneration plant and releasing a low-pressure (LP) exhaust gases stream comprising a mixture of nitrogen, oxygen, carbon dioxide and water vapor at a high temperature;
recovering an exhaust waste energy through producing the remainder of the gross power output of said polygeneration plant, converting the LP exhaust gases stream into a useful refrigerant and using said refrigerant for producing a liquefied MG (LMG) co-product from a major part of a processed MG;
harnessing a minor non-liquefied part of the processed MG as the fuel for the selected ICE;
providing a net power output of the polygeneration plant at a level which is equal to or above a power output of the selected ICE operated in a simple cycle mode; and
providing a power output of the polygeneration plant re-counted with consideration of a power equivalent of the LMG co-product at a level which is above a power output of the selected ICE operated in a conventional combined cycle mode.

### Claim 2 (depends on 1)

A method as in claim 1, wherein said processing the supplied MG comprises the following steps:
dehydration of the supplied MG;
reducing a carbon dioxide content in the supplied MG down to a level selected in accordance with a rated pressure of said LMG co-product;
selecting a value of a high pressure (HP) of the supplied MG prior to its liquefaction with regard to a pressure value of said LP exhaust gases stream released from the ICE;
on-demand compressing the supplied MG up to the selected HP value, resulting in forming a HP MG stream; and
pre-cooling said HP MG stream prior to its liquefying.

### Claim 3 (depends on 1)

A method as in claim 1, wherein producing the LMG co-product comprises the following steps:
liquefying the whole of said HP MG stream with use of the refrigerant formed from the LP exhaust gases stream, resulting in formation of a high-pressure liquefied MG (HP LMG) stream;
two-stage depressurizing the HP LMG stream down to the rated pressure of the LMG co-product, resulting in forming a two-phase MG gas stream at said rated pressure;
separating said two-phase MG gas stream into a vapor MG stream and a liquefied MG stream;
using said vapor MG stream, as the non-liquefied part of the processed MG, for said pre-cooling the HP MG stream and fueling the ICE; and
using said liquefied MG stream as the LMG co-product of the polygeneration plant.

### Claim 4 (depends on 1)

A method as in claim 1, wherein the following processes are performed in deciding on the twin-shaft gas turbine as the ICE for the polygeneration plant:
supplying the polygeneration plant with the atmospheric air which is pressurized up to a high pressure (HP) by a turbine compressor and completely used as a HP combustion air in said gas turbine;
supplying the turbine combustor with the non-liquefied part of the processed MG as the fuel for the gas turbine;
burning a mixture of said fuel and the HP combustion air in a turbine combustor with generating a combustion gases stream escaped the turbine combustor at the HP and a top cycle temperature;
expanding the combustion gases down to a low pressure (LP) in the HP turbine expander, resulting in producing said first part of the gross power output of said polygeneration plant which is fully consumed by said turbine compressor;
releasing the LP exhaust gases stream from the HP turbine expander at the high temperature;
recovering a thermal energy of the LP exhaust gases stream in a heat recovery steam generator (HRSG) of a steam bottoming cycle, resulting in producing a second part of the gross power output of said polygeneration plant; and
recovering a pressure energy of the LP exhaust gases stream in a LP expander, being performed as a part of converting the LP exhaust gases stream into the useful refrigerant and resulting in production of a third part of the gross power output of said polygeneration plant.

### Claim 5 (depends on 1)

A method as in claim 1, wherein the following processes are performed in deciding on the lean burn supercharged reciprocating gas engine as the ICE for the polygeneration plant:
supplying the polygeneration plant with the atmospheric air which is pressurized up to a low pressure (LP) by a separate LP air compressor;
using a major part of a LP atmospheric air as a LP combustion air for said gas engine;
supplying the gas engine with the non-liquefied part of the processed MG as the fuel for the gas engine;
mixing the LP combustion air with said fuel and their following compressing in the gas engine up to a high pressure (HP);
burning a HP mixture of said fuel and combustion air in said gas engine, resulting in generating a combustion gas at a top cycle pressure and a top cycle temperature;
expanding the combustion gas in the gas engine down to a low pressure (LP), resulting in producing said first part of the gross power output of said polygeneration plant and releasing the LP exhaust gases stream from the gas engine at the high temperature;
recovering a thermal energy of the LP exhaust gases stream in the HRSG of the steam bottoming cycle, resulting in producing the second part of the gross power output of said polygeneration plant;
mixing the LP exhaust gases stream escaped said HRSG with a minor part of the LP atmospheric air escaped said LP air compressor, resulting in forming a LP gaseous stream;
recovering a pressure energy of the LP gaseous stream in a LP expander, being performed as a part of converting the LP gaseous stream into the useful refrigerant and resulting in production of the third part of the gross power output of said polygeneration plant; and
consuming the second and third parts of the gross power output of said polygeneration plant for driving said LP air compressor.

### Claim 6 (depends on 4)

A method as in the claim 4, wherein said converting the LP exhaust gases stream into the useful refrigerant comprises the following steps:
cooling the LP exhaust gases stream escaped said HRSG by the water or atmospheric air with draining a formed condensate;
drying the LP exhaust gases stream, resulting in capturing a water vapor in a pressure swing adsorber, and following chilling a dried LP exhaust gases stream below 0° C. in a cold regenerator so, forming a dried and chilled LP exhaust gases stream upstream of said LP expander;
said expanding the dried and chilled LP exhaust gases stream in the LP expander, resulting in forming a deeply cooled non-pressurized exhaust gases stream, as the useful refrigerant, at the outlet of said LP expander;
recovering a cold thermal energy of said refrigerant first for the producing the LMG co-product and then for said chilling the dried LP exhaust gases stream in the cold regenerator;
using said refrigerant escaped the cold regenerator for removing the captured water vapor from the pressure swing adsorber; and
exhausting the refrigerant together with the water vapor through use of an exhaust fan.

### Claim 7 (depends on 5)

A method as in the claim 5, wherein said converting the LP gaseous stream into the useful refrigerant comprises the following steps:
cooling the LP gaseous stream by the water or atmospheric air with draining a formed condensate;
drying the LP gaseous stream with capturing a water vapor in a pressure swing adsorber and following chilling a dried LP gaseous stream below 0° C. in a cold regenerator so, forming a dried and chilled LP gaseous stream upstream of said LP expander,
said expanding the dried and chilled LP gaseous stream in the LP expander, resulting in forming a deeply cooled non-pressurized gaseous stream, as the useful refrigerant, at the outlet of said LP expander,
recovering a cold thermal energy of said refrigerant first for the producing the LMG co-product and then for said chilling the dried LP gaseous stream in the cold regenerator;
using said refrigerant escaped the cold regenerator for removing the captured water vapor from the pressure swing adsorber; and
exhausting the refrigerant together with the water vapor using an exhaust fan.

### Claim 8 (depends on 5)

A method as in the claim 5, wherein an enhanced yield of the LMG co-product of the polygeneration plant with the gas engine, as the selected ICE, is achieved by increasing a flowrate of the refrigerant and performed through combination of the following processes:
supplementary firing an additional fuel in the LP exhaust gases stream ahead of the HRSG;
increasing a steam capacity of the HRSG, resulting in producing an extra power by a steam turbine of the steam bottoming cycle;
increasing a flowrate value of said minor part of the LP atmospheric air produced by the LP air compressor and mixed with the LP exhaust gases stream escaped the HRSG;
increasing a flowrate value of the dried and chilled LP gaseous stream at the inlet of the LP expander, resulting in producing an extra power by said LP expander;
increasing a flowrate value of the deeply cooled non-pressurized gaseous stream, as the useful refrigerant, at the outlet of said LP expander; and
serving the enhanced needs of the LP air compressor for a power input through using the extra power produced by the steam turbine and LP expander.