Liquid crystal aligning agent, liquid crystal alignment film, and liquid crystal display element
AssigneeNissan Chemical Industries, Ltd.
InventorTatsuya Nagi
Life of this patent
Estimating the term…
Abstract
The present invention relates to a polymer composition which contains (A) a photosensitive side-chain polymer that exhibits liquid crystallinity in a predetermined temperature range and has a repeating unit comprising a vertically aligning group, and (B) an organic solvent. The present invention provides: a liquid crystal alignment film which has excellent tilt angle characteristics, while being provided with alignment controllability with high efficiency; a polymer composition which enables the achievement of this liquid crystal alignment film; a twisted nematic liquid crystal display element; and a vertical field switching mode liquid crystal display element.
Claims11
A polymer composition, comprising:
- (A) a side chain polymer which is a photosensitive side chain polymer exhibiting liquid crystallinity in a predetermined temperature range and has a repeating unit comprising from 0.1 to 50 mol % of a vertically alignable group;
- and
- (B) an organic solvent;
- wherein the vertically alignable group is
- at least one member selected from the group consisting of alkyl having 6 to 17 carbon atoms:
- wherein component (A) comprises one or more photosensitive sidechains of the following formula:
- wherein A, B, and D each independently represent a single bond, —O—, —CH2—, —COO—, —OCO—, —CONH—, —NH—CO—, —CH═CH—CO—O—, or —O—CO—CH═CH—;
- S represents an alkylene group having 1 to 12 carbon atoms, and a hydrogen atom bonded thereto may be replaced with a halogen group;
- T represents a single bond or an alkylene group having 1 to 12 carbon atoms, and a hydrogen atom bonded thereto may be replaced with a halogen group;
- Y2 represents a group selected from the group consisting of a divalent benzene ring, a naphthalene ring, a biphenyl ring, a furan ring, a pyrrole ring, an alicyclic hydrocarbon having 5 to 8 carbon atoms, and a combination thereof, and hydrogen atoms bonded thereto may be each independently substituted with —NO2, —CN, —CH═C(CN)2, —CH═CH—CN, a halogen group, an alkyl group having 1 to 5 carbon atoms, or an alkyloxy group having 1 to 5 carbon atoms;
- R represents hydroxy;
- P and Q each independently represent a group selected from the group consisting of a divalent benzene ring, a naphthalene ring, a biphenyl ring, a furan ring, a pyrrole ring, an alicyclic hydrocarbon having 5 to 8 carbon atoms, and a combination thereof, and when X is CH═CH—CO—O— or —O—CO—CH═CH—, P or Q on a side to which —CH═CH— is bonded is an aromatic ring;
- and
- l1 represents 0 or 1;
- l2 represents an integer of 0 to 2;
- when both l1 and l2 are 0, A also represents a single bond when T is a single bond;
- when l1 is 1, B also represents a single bond when T is a single bond.
Dependencies are inferred from the claim text.