Immobilized metalloporphyrin catalyst and its utilization in maleic acid preparation
AssigneeJiangnan University
InventorsHaijun Wang, Yi Huang, Chunyan Wu, Wenwen Yuan
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AssigneeJiangnan University
InventorsHaijun Wang, Yi Huang, Chunyan Wu, Wenwen Yuan
Estimating the term…
The present disclosure discloses an immobilized metalloporphyrin catalyst and its utilization in maleic acid preparation, belonging to the technical field of metalloporphyrin catalytic application. The immobilized metalloporphyrin catalyst is used for catalyzing furfural to prepare maleic acid and is good in catalytic effect, mild in reaction conditions and capable of greatly reducing the energy consumption required in the prior art. The catalyst disclosed by the present disclosure can provide a good microenvironment for a reaction, so that the yield and selectivity of maleic acid are increased; and according to a method disclosed by the present disclosure, the conversion ratio of furfural is 20.4%-95.6%, the yield of maleic acid is 10%-56.1%, and the selectivity is 43.6%-76.1%. Meanwhile, the catalyst is easy to separate and environmentally friendly and may be recycled for many times.
The method of using an immobilized metalloporphyrin catalyst, comprising oxidizing furfural with the immobilized metalloporphyrin catalyst, and obtaining maleic acid;
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