Lubricating oils
AssigneeCroda, Inc.
InventorsXin Chen, Alexei Nikolaevich Kurchan, Zhongqi Shen
Life of this patent
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Abstract
A lubricating composition comprises an amide and at least one additive. The amide is the reaction product of a secondary, branched amine and a carboxylic acid. The carboxylic acid may be a monocarboxylic acid or a dicarboxylic acid, including dimer acid. The amide is hydrolytically stable, and may be used to increase the hydrolytic stability of the lubricant composition. Alternatively, the amide may be used to increase the additive solubility or detergency of the lubricant composition.
Claims13
A lubricating composition comprising:
- a) 5 wt % to 20 wt % based on the total weight of the composition of an amide, where the amide is a liquid at room temperature, has a pour point measured according to the method set out in ASTM D97 of not higher than −20° C. and is of Formula (Ia) or (Ib)
- wherein:
- R1 and R2 are independently selected from the group consisting of an isopropyl group and a C3 to C18 branched, saturated or unsaturated, hydrocarbyl group;
- R3 is selected from the group consisting of C3 to C23 linear or branched, saturated or unsaturated hydrocarbyl groups;
- R4 is selected from the group consisting of C1 to C12 linear or branched, saturated or unsaturated hydrocarbylene groups;
- and
- n is 0 or 1;
- b) 0.5 wt % to 2 wt % based on the total weight of the composition of at least one additive that is a molybdenum dialkyldithiocarbamate;
- and
- c) 40 wt % to 95 wt % based on the total weight of the composition of a base oil comprising a lubricant component selected from API Groups IV, IV+ and mixtures of IV or IV+ with one or more of API Groups I, II, III, III+ and V, wherein for the mixtures, the Group IV or IV+ component is the majority component.
A method of increasing the additive solubility or detergency of a lubricant composition which comprises adding to the lubricant composition:
- a) 5 wt % to 20 wt % based on the total weight of the composition of an amide, where the amide is a liquid at room temperature, has a pour point measured according to the method set out in ASTM D97 of not higher than −20° C. and is of Formula (Ia) or (Ib)
- wherein:
- R1 and R2 are independently selected from the group consisting of an isopropyl group and a C3 to C18 branched, saturated or unsaturated, primary hydrocarbyl group;
- R3 is selected from the group consisting of C3 to C23 linear or branched, saturated or unsaturated hydrocarbyl groups;
- R4 is selected from the group consisting of C1 to C12 linear or branched, saturated or unsaturated hydrocarbylene groups;
- and
- n is 0 or 1;
- and
- b) 0.5 wt % to 2 wt % based on the total weight of the composition of at least one additive that is a molybdenum dialkyldithiocarbamate,
- wherein the lubricant composition comprises 40 wt % to 95 wt % based on the total weight of the composition of a base oil comprising a lubricant component selected from API Groups IV, IV+ and mixtures of IV or IV+ with one or more of API Groups I, II, III, III+ and V, wherein for the mixtures, the Group IV or IV+ component is the majority component.
A method of producing a hydrolytically stable lubricant composition comprising:
- a) reacting a secondary, branched amine and a carboxylic acid to form an amide;
- and
- b) adding at least one additive that is a molybdenum dialkyldithiocarbamate to the amide,
- wherein the secondary, branched amine reactant has the formula (II):
- wherein R1 and R2 are independently selected from the group consisting of an isopropyl group, and a C3 to C18 branched, saturated or unsaturated, hydrocarbyl group, and
- wherein the amide is a liquid at room temperature, has a pour point measured according to the method set out in ASTM D97 of not higher than −20° C. and is of Formula (Ia) or (Ib):
- wherein:
- R1 and R2 are as defined;
- R3 is selected from the group consisting of C3 to C23 linear or branched, saturated or unsaturated hydrocarbyl groups;
- R4 is selected from the group consisting of C1 to C12 linear or branched, saturated or unsaturated hydrocarbylene groups;
- and
- n is 0 or 1, and
- wherein:
- the amide is present in the lubricant composition in an amount of 5 wt % to 20 wt % based on the total weight of the composition,
- the additive is present in the lubricant composition in an amount of 0.5 wt % to 2 wt % based on the total weight of the composition, and
- the lubricant composition comprises 40 wt % to 95 wt % based on the total weight of the composition of a base oil comprising a lubricant component selected from API Groups IV, IV+ and mixtures of IV or IV+ with one or more of API Groups I, II, III, III+ and V, wherein for the mixtures, the Group IV or IV+ component is the majority component.
Dependencies are inferred from the claim text.