Electrode active material, all solid fluoride ion battery, and method for producing electrode active material
AssigneeToyota Jidosha Kabushiki Kaisha
InventorHidenori Miki
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Abstract
An object of the present disclosure relates to an electrode active material that has excellent discharge capacity and is used in an all solid fluoride ion battery. The present disclosure achieves the object by providing an electrode active material to be used in an all solid fluoride ion battery, the electrode active material comprising: an active material region that contains an active material component including a layered structure; and a coating region positioned in a surface side of the active material region; and a fluorine concentration in the coating region is higher than a fluorine concentration in the active material region.
Claims13
An all solid fluoride ion battery comprising:
- a cathode active material layer containing a cathode active material, an anode active material layer containing an anode active material, and a solid electrolyte layer formed between the cathode active material layer and the anode active material layer;
- wherein
- the cathode active material or the anode active material is an electrode active material comprising:
- an active material region that contains an active material component including a layered structure;
- and
- a coating region positioned in a surface side of the active material region;
- the electrode active material functions as an active material by intercalation and desorption of fluoride ions;
- the active material component includes a layered Perovskite structure and a crystal phase represented by An+1BnO3n+1−αFx, in which A includes at least one selected from the group consisting of an alkali earth metal element and a rare earth element, B includes at least one selected from the group consisting of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb, n is 1 or 2, α satisfies 0≤α≤2, and x satisfies 0≤x≤2.2, and
- wherein a fluorine concentration (atomic %) in the active material region is regarded as F1, and wherein a fluorine concentration (atomic %) in the coating region is regarded as F2, such that a fluorinating ratio F2/F1 is 1.5 or higher.
Dependencies are inferred from the claim text.