# US 11,079,695 B2 · Toner external additive and toner

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- Number: US 11,079,695 B2
- Document ID: US11079695B2
- Status: Granted
- Kind: B2
- Application number: 16/819,736
- Filed: 2020-03-16
- Published: 2020-09-24
- Granted: 2021-08-03
- Earliest claimed: 2019-03-19
- Assignees: Canon Kabushiki Kaisha
- Applicants: Canon Kabushiki Kaisha
- Inventors: Kazuyuki Sato; Masao Suzuki; Masashi Hirose
- Web page: https://patentgrep.com/patent/US11079695B2

## CPC

- G03G 9/09716: {treated with organic compounds}
- G03G 9/1138: {Non-macromolecular organic components of coatings}
- G03G 9/09708: {Inorganic compounds}
- G03G 9/09725: {Silicon-oxides; Silicates}
- G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY

## Abstract

Provided is a toner external additive containing a base material, wherein the base material is surface-treated with an isocyanurate ring-bearing silane coupling agent, and a toner including a toner particle and a toner external additive on a surface of the toner particle, wherein the toner external additive is the aforementioned toner external additive.

## Claims

### Claim 1

A toner, comprising:
a toner particle; and
a toner external additive on a surface of the toner particle, the toner external additive comprising a base material that is surface-treated with an isocyanurate ring-bearing silane coupling agent.

### Claim 2 (depends on 1)

The toner according to claim 1, wherein an amount of the base material treated with the silane coupling agent is 0.1 to 30.0 mass parts per 100 mass parts of the base material.

### Claim 3 (depends on 1)

The toner according to claim 1, wherein the silane coupling agent is at least one member selected from the group consisting of a silane compound represented by formula (1) and hydrolyzates of the silane compound
where each R independently represents a C1-6 monovalent hydrocarbon group, n represents an integer from 1 to 10, and m represents 0 or 1.

### Claim 4 (depends on 1)

The toner according to claim 1, wherein the silane coupling agent is at least one member selected from the group consisting of tris(3-trimethoxysilylpropyl) isocyanurate and hydrolyzates thereof, and tris(3-triethoxysilylpropyl) isocyanurate and hydrolyzates thereof.

### Claim 5 (depends on 1)

The toner according to claim 1, wherein the base material is an inorganic fine particle.

### Claim 6 (depends on 5)

The toner according to claim 5, wherein the inorganic fine particle is at least one member selected from the group consisting of silica fine particles, alumina fine particles, titania fine particles, zinc oxide fine particles, strontium titanate fine particles, cerium oxide fine particles, calcium carbonate fine particles, and silica-alumina mixed oxide fine particles.